Evidence for the participation of a high-valent iron-oxo species in stereospecific alkane hydroxylation by a non-heme iron catalyst

被引：188

作者：

Chen, K

Que, L

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

[2] Univ Minnesota, Ctr Met Biocatalysis, Minneapolis, MN 55455 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 15期

关键词：

D O I：

10.1039/a901678c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The incorporation of O-18 from (H2O)-O-18 into the product of stereospecific alkane hydroxylation by [Fe-II(bpmen)-(CH3CN)(2)](ClO4)(2)-H2O2 provides the first strong evidence for the participation of a high-valent iron-oxo species in the mechanism of a non-heme iron catalyst.

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页码：1375 / 1376

页数：2

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