Spherical Structures Composed of Multiwalled Carbon Nanotubes: Formation Mechanism and Catalytic Performance

被引:52
作者
Zhang, Jian [2 ]
Wang, Rui [2 ]
Liu, Enze
Gao, Xufeng [2 ]
Sun, Zhenhua [2 ]
Xiao, Feng-Shou [1 ]
Girgsdies, Frank [3 ]
Su, Dang Sheng [2 ,3 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
[2] Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China
[3] Max Planck Gesell, Dept Inorgan Chem, Fritz Haber Inst, D-14195 Berlin, Germany
关键词
carbon nanotubes; heterogeneous catalysis; monoliths; oxidative dehydrogenation; solid-phase synthesis; ACTIVATED CARBON; GROWTH; DEHYDROGENATION; NANOFIBERS; CHEMISTRY;
D O I
10.1002/anie.201200969
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Structured catalyst: A new strategy was used to produce carbon nanotube monoliths by a solid-phase process that was well characterized by in situ techniques. The synthesized spherical nanoparticles display extremely high selectivity in the oxidative dehydrogenation (ODH) of ethylbenzene (see scheme). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:7581 / 7585
页数:5
相关论文
共 29 条
[1]  
[Anonymous], ANGEW CHEM
[2]  
[Anonymous], 2007, ANGEW CHEM
[3]   Mechanism for the growth of multiwalled carbon-nanotubes from carbon black [J].
Buchholz, DB ;
Doherty, SP ;
Chang, RPH .
CARBON, 2003, 41 (08) :1625-1634
[4]  
Endo M., 1996, CARBON NANOTUBES, DOI DOI 10.1002/btpr.1836
[5]   Simple Synthesis of Multiwalled Carbon Nanotubes from Natural Resources [J].
Endo, Morinobu ;
Takeuchi, Kenji ;
Kim, Yoong Ahm ;
Park, Ki Chul ;
Ichiki, Takuya ;
Hayashi, Takuya ;
Fukuyo, Tomoyuki ;
Linou, Satoshi ;
Su, Dang Sheng ;
Terrones, Mauricio ;
Dresselhaus, Mildred S. .
CHEMSUSCHEM, 2008, 1 (10) :820-822
[6]   HIGH-RESOLUTION ELECTRON-MICROSCOPY STUDIES OF A MICROPOROUS CARBON PRODUCED BY ARC-EVAPORATION [J].
HARRIS, PJF ;
TSANG, SC ;
CLARIDGE, JB ;
GREEN, MLH .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1994, 90 (18) :2799-2802
[7]   Study of multiwalled graphite nanotubes and filaments formation from carbonized products of polyvinyl alcohol via catalytic graphitization at 600-800°C in nitrogen atmosphere [J].
Krivoruchko, OP ;
Maksimova, NI ;
Zaikovskii, VI ;
Salanov, AN .
CARBON, 2000, 38 (07) :1075-1082
[8]   Carbon nanotube synthesis via the catalytic CVD method:: A review on the effect of reaction parameters [J].
Öncel, Ç ;
Yürüm, Y .
FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES, 2006, 14 (01) :17-37
[9]   Carbonization of PAN grafted uniform crosslinked polystyrene microspheres [J].
Partouche, Eran ;
Margel, Shlomo .
CARBON, 2008, 46 (05) :796-805
[10]   Growing mechanism of CNTs:: a kinetic approach [J].
Pérez-Cabero, M ;
Romeo, E ;
Royo, C ;
Monzón, A ;
Guerrero-Ruíz, A ;
Rodríguez-Ramos, I .
JOURNAL OF CATALYSIS, 2004, 224 (01) :197-205