Enhancement of multiferroic and magnetocapacitive properties in nanocrystalline Mg-doped GaFeO3

被引:19
|
作者
Han, T. C. [1 ]
Chung, Y. D. [1 ]
Lee, Y. C. [1 ]
机构
[1] Natl Univ Kaohsiung, Dept Appl Phys, Kaohsiung 81148, Taiwan
关键词
Multiferroic; Magnetoelectric; Ferrimagnetic; Ferroelectricity; Gallium ferrite; MAGNETIC-PROPERTIES;
D O I
10.1016/j.jallcom.2016.09.111
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have study the effect of Mg doping on structural, magnetic, electric and magnetocapacitive properties of nanocrystalline Ga1-xMgxFeO3 (GMFO, 0 <= x <= 0.10) prepared by a modified Pechini method. The presence of a single crystalline phase identified as the orthorhombic structure with Pc21(n) space in all the GMFO samples. Magnetization measurements reveal that with increasing Mg-content up to 0.10, the ferrimagnetic transition temperature (T-C) increases from 302 to 325 K. It is also found that the Mg-doped GaFeO3 (GFO) samples exhibit the characteristics of ferroelectricity at room temperature. Furthermore, Mg substitution in GFO brings in the balance of structural distortion, cation distribution, and magnetic exchange interaction, which affects both ferrimagnetism and ferroelectricity. The simultaneous enhancement of magnetization, electric polarization and magnetocapacitance of Mg-doped GFO samples are prominent candidates for the applications of multiferroic devices. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:569 / 572
页数:4
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