Baeyer-Villiger oxidations in ionic liquids. A facile conversion of ketones to esters and lactones

被引：33

作者：

Yadav, JS ^{[1
]}

Reddy, BVS ^{[1
]}

Basak, AK ^{[1
]}

Narsaiah, AV ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Div Organ Chem, Hyderabad 500007, Andhra Pradesh, India

来源：

CHEMISTRY LETTERS | 2004年 / 33卷 / 03期

关键词：

D O I：

10.1246/cl.2004.248

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A variety of cyclic and acyclic ketones underwent readily oxidation with m-chloroperbenzoic acid (m-CPBA) in ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate [bmim]BF4 to afford esters/lactones with high selectivity, ease of product separation and in excellent chemical yields. The reaction proceeded smoothly in ionic liquid without the need of any additional acid or base catalyst. The ketones show enhanced reactivity in ionic liquids thereby reducing reaction times and improving the yields significantly.

引用

页码：248 / 249

页数：2

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