Synthesis, Crystal Structure and Magnetic Property of a Sandwich-Like Cyanide-Bridged Fe(III)-Mn(II) Complex

被引：4
作者：
Zhang, Daopeng [1 ]
Zhao, Zengdian [1 ]
Chen, Xia [1 ]
机构：
[1] Shandong Univ Technol, Coll Chem Engn, Zibo 255049, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2013年 / 25卷 / 06期
关键词：
Cyanide-bridged; Crystal structure; Magnetic property; DESIGN;
D O I：
10.14233/ajchem.2013.13622
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A trinuclear cyanide-bridged Fe(III)-Mn(II) complex has been synthesized with pyridine carboxamide trans-dicyanide iron building block and structurally characterized as trinuclear sandwich-like, in which the two cyanide-containing building blocks acting as a monodentate ligand were coordinated face to face to central Mn(II) ion. Investigation over its magnetic property reveals the antiferromagnetic magnetic coupling between the cyanide-bridged neighboring FE(III) and Mn(II) ions.
引用
收藏
页码：3509 / 3510
页数：2
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