Cationic phosphine-imine rhodium(I) complexes and their activity on catalysis of phenylacetylene polymerization

被引：3

作者：

Reddy, KR ^{[1
]}

Lin, CF ^{[1
]}

Lee, GH ^{[1
]}

Peng, SM ^{[1
]}

Chen, JT ^{[1
]}

Liu, ST ^{[1
]}

机构：

[1] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2001年 / 48卷 / 6A期

关键词：

rhodium; polymerization; phenylacetylene; alkyne; aqueous medium;

D O I：

10.1002/jccs.200100146

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of phosphine-imine rhodium(1) complexes have been prepared and characterized by both spectroscopic and X-ray single crystal analyses. Their activity on catalytic polymerization of phenylacetylene is investigated. The study of the solvent effect on polymerization shows that aqueous medium can increase the productivity of polymer.

引用

页码：997 / 1002

页数：6

共 36 条

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