Determination of Polyurethane Foam Growth Kinetics by a Simple Column Height Test

In the present work, the height of foam column has been used to monitor the reaction of the isocyanate group. Kinetic modeling describes the conversion versus time curves. The global reaction can be divided into two different paths: the blowing reaction and the polymerization. The kinetics of the reaction of toluene diisocyanate with a polypropylene glycol has been studied with auxiliary blowing agents; the concentration of NCO and OH groups could be considered equivalent during all the experiments as a model for similar polyurethane systems. Despite the complexity of the system in which different kinetic orders are possible, as well a physically controlled diffusion process, data were fitted to a simple kinetic model of an apparent order. The results obtained have enabled us to propose a reaction path and catalyzed second-order kinetic model. (C) 2015 Wiley Periodicals, Inc.