On the reaction of 1,3-dimethyl-2-iminoimidazoline derivatives with CS2

被引：0

作者：

Kuhn, N

Fawzi, R

Steimann, M

Wiethoff, J

机构：

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1997年 / 52卷 / 05期

关键词：

imidazoles; carbon disulfide; x-ray;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,3-Dimethyl-2-iminoimidazoline (4, ImNH) reacts with CS2 to give the imidazolium salt [ImNH(2)][(ImNCS(2))(2)H] (7) in which two dithioformimide fragments are linked by a hydrogen bridge. From the trimethylsilyl derivative ImNSiMe(3) (11) and CS2 the adduct ImNSiMe(3) . CS2 (12) is obtained which reacts with oxygen to give the disulfide (ImNCS(2)) (14). The X-ray structures of 7 and 14 were determined.

引用

页码：609 / 614

页数：6

共 18 条

[11] Imidazole derivatives .17. - Synthesis and properties of dichloro(1,3-dimethyl-2-imidazol-2-ylidenimino)phosphane - A methylenamino substituent with uncommon donor properties
Kuhn, N
Fawzi, R
Steimann, M
Wiethoff, J
[J]. CHEMISCHE BERICHTE, 1996, 129 (04) : 479 - 482
[12] Synthesis and structure of 2-imino-1,3-dimethylimidazoline
Kuhn, N
Fawzi, R
Steimann, M
Wiethoff, J
Blaser, D
Boese, R
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1995, 50 (12): : 1779 - 1784
[13] Imidazole derivatives .23. 2-iminoimidazoline derivatives of magnesium and aluminum
Kuhn, N
Fawzi, R
Steimann, M
Wiethoff, J
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (04): : 554 - 560
[14] KUHN N, 1994, Z NATURFORSCH B, V49, P1473
[15] KUHN N, 1997, J CHEM SOC CHEM COMM, P627
[16] KUHN N, IN PRESS PHOSPHORUS
[17] DI-TERT-BUTYL THIOKETONE
OHNO, A
NAKAMURA, K
NAKAZIMA, Y
OKA, S
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1975, 48 (08) : 2403 - 2404
[18] REACTION OF 4,4'-DIMETHOXYDIPHENYLMETHANIMINE WITH CARBON DISULFIDE
WILLIAMS, HB
YARBROUG.KN
CROCHET, KL
WELLS, DV
[J]. TETRAHEDRON, 1970, 26 (03) : 817 - &

← 1 2 →