On the reaction of 1,3-dimethyl-2-iminoimidazoline derivatives with CS2

被引：0
作者：
Kuhn, N
Fawzi, R
Steimann, M
Wiethoff, J
机构：
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1997年 / 52卷 / 05期
关键词：
imidazoles; carbon disulfide; x-ray;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
1,3-Dimethyl-2-iminoimidazoline (4, ImNH) reacts with CS2 to give the imidazolium salt [ImNH(2)][(ImNCS(2))(2)H] (7) in which two dithioformimide fragments are linked by a hydrogen bridge. From the trimethylsilyl derivative ImNSiMe(3) (11) and CS2 the adduct ImNSiMe(3) . CS2 (12) is obtained which reacts with oxygen to give the disulfide (ImNCS(2)) (14). The X-ray structures of 7 and 14 were determined.
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页码：609 / 614
页数：6
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