Generation of C-60 radical cation and radical adduct of dichloro- or monochloromethyl radical to C-60: Pulse radiolysis and laser photolysis of C-60 in polar chloromethane

被引：4
作者：
Lian, ZR
Yao, SD
Lin, WZ
Wang, WF
Lin, NY
机构：
[1] Laboratory of Radiation Chemistry, Shanghai Inst. of Nuclear Research, Academia Sinica, Shanghai
来源：
RADIATION PHYSICS AND CHEMISTRY | 1997年 / 50卷 / 03期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1016/S0969-806X(97)00020-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The radical cation of C-60 is generated either via hole transfer from the radical cation of polar chlorinated methane to C-60 or via electron transfer from the triplet of C-60 to electrophilic polar chlorinated methane. The radical adducts (CHCl2)-C-. and (CH2Cl)-C-. of C-60 were produced via a similar mechanism to the generation of the radical adduct (.)[C-60-CCl3] in CCl4. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：245 / 247
页数：3
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