Efficient nickel/N-heterocyclic carbene catalyzed C-S cross-coupling

被引：69

作者：

Guan, Pei ^{[1
,2
]}

Cao, Changsheng ^{[1
,2
]}

Liu, Yun ^{[1
,2
]}

Li, Yunfei ^{[1
,2
]}

He, Pan ^{[1
,2
]}

Chen, Qian ^{[1
,2
]}

Liu, Gang ^{[1
,2
]}

Shi, Yanhui ^{[1
,2
,3
]}

机构：

[1] Jiangsu Normal Univ, Sch Chem & Chem Engn, Xuzhou 221116, Jiangsu, Peoples R China

[2] Jiangsu Normal Univ, Jiangsu Key Lab Green Synthet Chem Funct Mat, Xuzhou 221116, Jiangsu, Peoples R China

[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

来源：

TETRAHEDRON LETTERS | 2012年 / 53卷 / 45期

基金：

中国国家自然科学基金;

关键词：

C-S bond formation; Cross-coupling; Thiols; Aryl halides; ARYL HALIDES; BOND FORMATION; THIOLS; LIGAND; COMPLEXES; SULFIDES; IODIDES; CARBON;

D O I：

10.1016/j.tetlet.2012.08.055

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cross-coupling reaction of aryl halides with aliphatic and aromatic thiols catalyzed by readily available Ni(OAc)(2) with N-heterocyclic carbene (NHC) is reported. Ni(OAc)(2)/NHC catalyst showed good activities toward various aryl halides in C-S coupling reaction, even with aryl chlorides. Reactions occurred in excellent yields, broad scope, and high tolerance of functional groups. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：5987 / 5992

页数：6

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