Dodecyl sulfate-induced fast faradic process in nickel cobalt oxide-reduced graphite oxide composite material and its application for asymmetric supercapacitor device

被引:345
作者
Wang, Xu [1 ]
Liu, Wan Shuang [1 ]
Lu, Xuehong [1 ]
Lee, Pooi See [1 ]
机构
[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
关键词
HIGH-PERFORMANCE SUPERCAPACITORS; LAYERED DOUBLE HYDROXIDES; HIGH-ENERGY DENSITY; ELECTROCHEMICAL CAPACITORS; ELECTRODE MATERIALS; CARBON NANOTUBES; HIGH-POWER; SHEETS; NANOSTRUCTURES; GRAPHENE/MNO2;
D O I
10.1039/c2jm35307e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this contribution, we report a facile preparation method of nickel cobalt oxide-reduced graphite oxide (NiCo2O4-rGO) composite material. A fast Faradic process has been realized by sodium dodecyl sulfate (SDS)-induced ultrasmall NiCo2O4 nanocrystals on rGO. As a result, this composite material gives a high specific capacitance of 1222 F g(-1) at 0.5 A g(-1) and 768 F g(-1) at 40 A g(-1), showing an outstanding rate capability. An asymmetric supercapacitor device with high energy and power densities has been successfully assembled based on NiCo2O4-rGO composite material and activated carbon. The optimized device shows a high energy density of 23.32 Wh kg(-1) at a power density of 324.9W kg(-1). In addition, this asymmetric device shows good stability towards multistage current charge-discharge cycles.
引用
收藏
页码:23114 / 23119
页数:6
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