Bubble nucleation on hydrophobic islands provides evidence to anomalously high contact angles of nanobubbles

被引:73
作者
Nam, Youngsuk [1 ]
Jua, Y. Sungtaek [1 ]
机构
[1] Univ Calif Los Angeles, Los Angeles, CA 90095 USA
基金
美国国家科学基金会;
关键词
D O I
10.1063/1.2981572
中图分类号
O59 [应用物理学];
学科分类号
摘要
We observe stable steady-periodic vapor bubble nucleation on islands of nanoscopically smooth hydrophobic materials microfabricated on a silicon substrate. The minimum surface superheat required for the onset of bubble nucleation is very low (similar to 9 degrees C), which cannot be explained by the established models of heterogeneous bubble nucleation. A modified bubble nucleation model indicates that the observed minimum superheat can be explained when one assumes the existence of a nanoscale interfacial gas phase with anomalously high contact angles (>160 degrees). Our data therefore provide independent evidence that supports previous atomic force microscopy and infrared spectroscopy studies of the topography of nanobubbles. (c) 2008 American Institute of Physics.
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页数:3
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