AC-Impedance Spectroscopic Analysis on the Charge Transport in CVD-Grown Graphene Devices with Chemically Modified Substrates

被引:3
|
作者
Min, Bok Ki [1 ,2 ]
Kim, Seong K. [1 ]
Kim, Seong Ho [1 ]
Kang, Min-A [1 ]
Noothongkaew, Suttinart [1 ]
Mills, Edmund M. [3 ]
Song, Wooseok [1 ]
Myung, Sung [1 ]
Lim, Jongsun [1 ]
Kim, Sangtae [3 ]
An, Ki-Seok [1 ]
机构
[1] Korea Res Inst Chem Technol, Film Mat Res Ctr, Yuseong 305600, Daejeon, South Korea
[2] Sungkyunkwan Univ, Dept Phys, 2066 Seobu Ro, Suwon 440746, Gyeonggi Do, South Korea
[3] Univ Calif Davis, Dept Chem Engn & Mat Sci, Davis, CA 95616 USA
基金
新加坡国家研究基金会;
关键词
CVD-grown graphene; ac-impedance spectroscopy; self-assembled monolayers (SAMs); charge transport; ac conduction; SELF-ASSEMBLED MONOLAYERS; VAPOR-DEPOSITION; TRANSISTORS; INTERFACE; MOBILITY; FILMS;
D O I
10.1021/acsami.6b03705
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A comprehensive study for the effect of interfacial buffer layers on the electrical transport behavior in CVD-grown graphene based devices has been performed by ac-impedance spectroscopy (IS) analysis. We examine the effects of the trap charges at graphene/SiO2 interface on the total capacitance by introducing self-assembled monolayers (SAMs). Furthermore, the charge transports in the polycrystalline graphene are characterized through the temperature-dependent IS measurement, which can be explained by the potential barrier model. The frequency-dependent conduction reveals that the conductivity of graphene is related with the mobility, which is limited by the scattering caused by charged adsorbates on SiO2 surface.
引用
收藏
页码:27421 / 27425
页数:5
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