Active versus Passive Substituent Participation in the Auxiliary-Mediated Asymmetric Synthesis of an Octahedral Metal Complex

被引：10

作者：

Chen, Liang-An ^{[1
]}

Ma, Jiajia ^{[1
]}

Celik, Mehmet Ali ^{[2
]}

Yu, Hong-Lang ^{[1
]}

Cao, Zexing ^{[1
]}

Frenking, Gernot ^{[2
]}

Gong, Lei ^{[1
]}

Meggers, Eric ^{[1
,2
]}

机构：

[1] Xiamen Univ, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China

[2] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2012年 / 7卷 / 11期

关键词：

asymmetric synthesis; chiral auxiliary; coordination chemistry; stereocontrol; sulfur; D-D BAND; COORDINATION CHEMISTRY; CHIRAL AUXILIARIES; RED-LIGHT; LIGANDS; CLEAVAGE; DNA;

D O I：

10.1002/asia.201200532

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ambiguous chirality transfer: A surprising reversal of chirality transfer from carbon to metal is reported in the asymmetric synthesis of a chiral ruthenium complex, affording the metal-centered configuration or δ depending only on the chemical composition of the side chain of a chiral salicyloxazoline auxiliary. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2523 / 2526

页数：4

共 35 条

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