Diffusion of Cu and interfacial reactions during reflow of Sn-8.5Zn-0.5Ag-0.01Al-0.1Ga alloy on Ni/Cu substrate

被引:8
作者
Mittal, Jagjiwan [1 ]
Lin, Kwang Lung [1 ]
机构
[1] Natl Cheng Kung Univ, Dept Mat Sci & Engn, Tainan 701, Taiwan
关键词
INTERMETALLIC COMPOUND FORMATION; ZN SOLDER JOINTS; SN-ZN; PHASE-EQUILIBRIA; AG SOLDER; AL SOLDER; MICROSTRUCTURE; EVOLUTION; SYSTEM; GROWTH;
D O I
10.1557/jmr.2012.68
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Reflow behavior of a Sn-8.5Zn-0.5Ag-0.01Al-0.1Ga (five-element) solder on the Ni/Cu substrate was investigated under different heating rates. Reflowed samples show decreased Zn and increased AgZn3 in the solder with a reduction in the heating rate. The Zn at the solder/substrate interface was found to be much lower than that in the Sn-Zn solder systems. Cu was observed to be diffused through the electroplated Ni layer and noticed only with the Ag-Zn compound in the solder. Ga was spotted at the interface in the Ag-Zn matrix, whereas Al was detected with the Zn at the interface. Small intermetallic compound (IMC) layer was formed at the interface; however, its amount enhanced with the reduction in the heating rate. Present study relates the reflow behavior of the five-element solder with the reactivity of different elements in the system and its influence on the formation of IMCs in the solder and at the solder/substrate interface.
引用
收藏
页码:1142 / 1148
页数:7
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