Electrochemical behavior of thin-film LiMn2O4 electrode in aqueous media

被引：82
作者：
Eftekhari, A [1 ]
机构：
[1] KN Toosi Univ Technol, Dept Chem, Tehran, Iran
来源：
ELECTROCHIMICA ACTA | 2001年 / 47卷 / 03期
关键词：
LiMn2O4; thin film; aqueous media; diffusion coefficient; electrochemical stability; lithium batteries;
D O I：
10.1016/S0013-4686(01)00774-5
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The electrochemical properties of a thin-film LiMn2O4 electrode were studied in an aqueous medium. The studies were done in a saturated aqueous medium to increase similarity of the electrolyte solution with a non-aqueous medium. The apparent diffusion coefficient was calculated and discussed for different potentials at the aqueous electrolyte. In addition, stability of the thin solid film was investigated during potential cycling, which indicates that the electrode is highly stable in aqueous medium as well as in non-aqueous media. The obtained results from electrochemical measurements indicate that the properties of the thin-film LiMn2O4 electrode in aqueous medium are similar to those that have been found in non-aqueous media. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：495 / 499
页数：5
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