What is a chemical substance and how is it formed?

被引:7
作者
Shevchenko, Vladimir Ya. [1 ]
机构
[1] Russian Acad Sci, Inst Silicate Chem, St Petersburg 199034, Russia
关键词
Nanoworld; Fundamental configurations; Multidimensional space; Self-assembly; Structural code; Icosahedrons; Convergence; Fundamental nanocluster;
D O I
10.1007/s11224-012-0094-z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The objects of nature are structurally generalized, especially the objects undergoing the stage of formation from atoms to macrosized species. No exceptions from a large number of the examined structures of inorganic and organic compounds, algae, plants, viruses, and other objects have been found out. For the majority of substances, the build-up starts from fundamental configurations, then clusters are formed, whereby the structure is assembled. The hierarchical construction is the basic principle irrespective of whether the whole structure is periodic or aperiodic. The spatial domain, in which the substance is formed, is tens to hundreds of nanometers in size, the type of the space geometry being inessential because in the small all the geometries are equivalent.
引用
收藏
页码:1089 / 1101
页数:13
相关论文
共 16 条
[1]   Anatomy of Thought, Mechanism, and Mathematics [J].
Andersson, Sten .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2011, 637 (7-8) :840-845
[2]  
Ball Philip, 2011, SCI AM MAGAZINE 1010, P48
[3]   Universally optimal distribution of points on spheres [J].
Cohn, Henry ;
Kumar, Abhinav .
JOURNAL OF THE AMERICAN MATHEMATICAL SOCIETY, 2007, 20 (01) :99-148
[4]  
Conway J.H., 1988, SPHERE PACKING LATTI
[5]  
Haeckel E, 1917, KRISTAL SEELEN
[6]  
Hardy GH, 1940, MATH APOLOGY, P153
[7]  
Kadomtsev BD, 1999, DYNAMICS INFORM, P427
[8]   Nanoscale double-core oligosilane dendrimers:: Synthesis, structure, and electronic properties [J].
Krempner, Clemens ;
Koeckerling, Martin .
ORGANOMETALLICS, 2008, 27 (03) :346-352
[9]   On complexity [J].
Mackay, AL .
CRYSTALLOGRAPHY REPORTS, 2001, 46 (04) :524-526
[10]  
Miras HN, 2010, SCIENCE, V327, P72, DOI [10.1126/science.1181735, 10.1126/science.11B1735]