Simple and Efficient Metal-free Hydroarylation and Hydroalkylation Using Strongly Acidic Ion-exchange Resin

被引:28
作者
Das, Biswanath [1 ]
Krishnaiah, Martha [1 ]
Laxminarayana, Keetha [1 ]
Damodar, Kongara [1 ]
Kumar, D. Nandan [1 ]
机构
[1] Indian Inst Chem Technol, Organ Chem Div 1, Hyderabad 500007, Andhra Pradesh, India
关键词
ELECTRON-RICH ARENES; CATALYZED HYDROARYLATION; SYNTHETIC METHODOLOGIES; UNACTIVATED OLEFINS; CHLORIDE; IODINE;
D O I
10.1246/cl.2009.42
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Higly efficient hydroarylation and hydroalkylation of styrenes with various arenes and 1,3-dicarbonyl compounds respectively have been developed using Amberlyst-15 as a heterogenous catalyst. The excellent yields, short reaction times, and high selectivity are the advantages of this method. The C-H functionalization has been achieved here under metal-free conditions.
引用
收藏
页码:42 / 43
页数:2
相关论文
共 21 条
[1]   Anti-markovnikov hydroarylation of unactivated olefins catalyzed by a bis-tropolonato iridium(III) organometallic complex [J].
Bhalla, G ;
Oxgaard, J ;
Goddard, WA ;
Periana, RA .
ORGANOMETALLICS, 2005, 24 (13) :3229-3232
[2]   Highly efficient iodine-catalyzed hydroarylation of arenes with styrenes [J].
Chu, Cheng-Ming ;
Huang, Wan-Ju ;
Liu, Ju-Tsung ;
Yao, Ching-Fa .
TETRAHEDRON LETTERS, 2007, 48 (39) :6881-6885
[3]   A remarkably simple N-formylation of anilines using polyethylene glycol [J].
Das, Biswanath ;
Krishnaiah, Maddeboina ;
Balasubramanyam, P. ;
Veeranjaneyulu, Boyapati ;
Kumar, D. Nandan .
TETRAHEDRON LETTERS, 2008, 49 (14) :2225-2227
[4]   Part 148 in the series "Studies on novel synthetic methodologies": selective acetylation of alcohols, Phenols and Amines and selective deprotection of aromatic acetates using silica-supported phosphomolybdic acid [J].
Das, Biswanath ;
Thirupathi, Ponnaboina ;
Kumar, Rathod Aravind ;
Laxminarayana, Keetha .
ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (17-18) :2677-2683
[5]   Studies on novel synthetic methodologies, part 85.: Iodine as an efficient catalyst for one-pot multicomponent synthesis of β-acetamido ketones [J].
Das, Biswanath ;
Reddy, K. Ravinder ;
Ramu, R. ;
Thirupathi, P. ;
Ravikanth, B. .
SYNLETT, 2006, (11) :1756-1758
[6]   Gold(III) chloride-catalyzed addition reactions of electron-rich arenes to methyl vinyl ketone [J].
Dyker, G ;
Muth, E ;
Hashmi, ASK ;
Ding, L .
ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (11) :1247-1252
[7]  
Dyker G, 1999, ANGEW CHEM INT EDIT, V38, P1699, DOI 10.1002/(SICI)1521-3773(19990614)38:12<1698::AID-ANIE1698>3.0.CO
[8]  
2-6
[9]   Nafenopin causes protein kinase c-mediated serine phosphorylation and loss of function of connexin 32 protein in rat hepatocytes without aberrant expression or localization [J].
Elcock, FJ ;
Deag, E ;
Roberts, RA ;
Chipman, JK .
TOXICOLOGICAL SCIENCES, 2000, 56 (01) :86-94
[10]   A convenient FeCl3-catalyzed hydroarylation of styrenes [J].
Kischel, J ;
Jovel, I ;
Mertins, K ;
Zapf, A ;
Beller, M .
ORGANIC LETTERS, 2006, 8 (01) :19-22