Observation of ferroelectricity and magnetoelectric coupling in Mn-doped orthochromite DyCr0.5Mn0.5O3

被引:16
作者
Yuan, B. [1 ]
Yang, J. [1 ]
Zuo, X. Z. [1 ]
Kan, X. C. [1 ]
Zhu, X. B. [1 ]
Dai, J. M. [1 ]
Song, W. H. [1 ]
Sun, Y. P. [1 ,2 ,3 ]
机构
[1] Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China
[2] Chinese Acad Sci, High Field Magnet Lab, Hefei 230031, Peoples R China
[3] Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
Ferroelectricity; Magnetoelectric effects; Multiferroics; SUPEREXCHANGE INTERACTION; WEAK FERROMAGNETISM; RAMAN-SPECTROSCOPY; MULTIFERROICS; TRANSITION;
D O I
10.1016/j.jallcom.2015.10.030
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We investigate the structural, magnetic, and magnetoelectric properties of DyCr0.5Mn0.5O3. DyCr0.5Mn0.5O3 exhibits ferroelectricity at the paramagnetic antiferromagnetic transition temperature, i.e., T-N = 74 K, demonstrating the polarization is driven by magnetic order. Furthermore, the ferroelectric polarization can be substantially influenced by applied magnetic fields indicating a strong magnetoelectric effect in DyCr0.5Mn0.5O3. It is demonstrated that the ferroelectricity in DyCr0.5Mn0.5O3 may stem from the spin-phonon coupling of Dy and Mn/Cr ions as evidenced by the temperature dependence of Raman phonon modes. The results manifest that DyCr0.5Mn0.5O3 is a potential candidate for magnetoelectric device applications. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:830 / 834
页数:5
相关论文
共 39 条
[1]   AN XPS STUDY OF THE ELECTRONIC-STRUCTURE OF THE ZNXCD1-XCR2S4 ZNXCD1-XCR2SE4 SPINEL SYSTEM [J].
AGOSTINELLI, E ;
BATTISTONI, C ;
FIORANI, D ;
MATTOGNO, G .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1989, 50 (03) :269-272
[2]   ANHARMONIC EFFECTS IN LIGHT-SCATTERING DUE TO OPTICAL PHONONS IN SILICON [J].
BALKANSKI, M ;
WALLIS, RF ;
HARO, E .
PHYSICAL REVIEW B, 1983, 28 (04) :1928-1934
[3]   Cr-doping-induced phase separation and MR effect in the manganite Pr0.5Ca0.5Mn1-xCrxO3 system [J].
Cao, Shixun ;
Li, Wenjuan ;
Zhang, Jincang ;
Kang, Baojuan ;
Gao, Tian ;
Jing, Chao .
JOURNAL OF APPLIED PHYSICS, 2007, 102 (05)
[4]   Multiferroics: a magnetic twist for ferroelectricity [J].
Cheong, Sang-Wook ;
Mostovoy, Maxim .
NATURE MATERIALS, 2007, 6 (01) :13-20
[5]   Weak ferromagnetism and magnetization reversal in YFe1-xCrxO3 [J].
Dasari, Nagamalleswararao ;
Mandal, P. ;
Sundaresan, A. ;
Vidhyadhiraja, N. S. .
EPL, 2012, 99 (01)
[6]   A THERMODYNAMIC THEORY OF WEAK FERROMAGNETISM OF ANTIFERROMAGNETICS [J].
DZYALOSHINSKY, I .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1958, 4 (04) :241-255
[7]   Chiral Domains in Cycloidal Multiferroic Thin Films: Switching and Memory Effects [J].
Fina, I. ;
Fabrega, L. ;
Marti, X. ;
Sanchez, F. ;
Fontcuberta, J. .
PHYSICAL REVIEW LETTERS, 2011, 107 (25)
[9]   Ferroelectricity and giant magnetocapacitance in perovskite rare-earth manganites [J].
Goto, T ;
Kimura, T ;
Lawes, G ;
Ramirez, AP ;
Tokura, Y .
PHYSICAL REVIEW LETTERS, 2004, 92 (25) :257201-1
[10]   Symmetry analysis for the Ruddlesden-Popper systems Ca3Mn2O7 and Ca3Ti2O7 [J].
Harris, A. B. .
PHYSICAL REVIEW B, 2011, 84 (06)