High precision measurements of carbon disulfide negative ion mobility and diffusion

被引:18
作者
Snowden-Ifft, D. P. [1 ]
Gauvreau, J. -L. [1 ]
机构
[1] Occidental Coll, Dept Phys, Los Angeles, CA 90041 USA
基金
美国国家科学基金会;
关键词
DRIFT; MIXTURES; CHAMBER;
D O I
10.1063/1.4803004
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
High precision measurements were made of reduced mobility, lateral and longitudinal diffusion of CS2- ions in 40 Torr CS2 and a 30-10 Torr CS2-CF4 gas mixture. The reduced mobility was found to be 0.4645 +/- 0.0006 cm(2) atm/s V in CS2 and 0.523 +/- 0.001 cm(2) atm/s V in the CS2-CF4 gas mixture at STP. The lateral diffusion temperatures for these two gases (295 +/- 15 K and 297 +/- 6 K) were found to be in good agreement with room temperature. By contrast longitudinal diffusion temperature was found to be slightly elevated (319 +/- 10 (stat) +/- 8 (sys) K and 310 +/- 20 (stat) +/- 6 (sys) K) though given the errors, room temperature diffusion cannot be ruled out. For lateral diffusion, significant capture distances (0.21 +/- 0.07 mm and 0.15 +/- 0.03 mm) were measured while for longitudinal diffusion the results were not conclusive. (C) 2013 AIP Publishing LLC.
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页数:8
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