Efficient clay supported Pd nanoparticles as heterogeneous catalyst for arylation of alkenes

被引:11
作者
Ghiaci, Mehran [1 ]
Ansari, Fatemeh [1 ]
Sadeghi, Zahra [2 ]
Gil, A. [3 ]
机构
[1] Isfahan Univ Technol, Dept Chem, Esfahan 8415683111, Iran
[2] Payam Nor Univ, Esfahan, Iran
[3] Univ Publ Navarra, Dept Appl Chem, Pamplona 31006, Spain
关键词
Amine modified bentonite; Palladium catalyst; Alkenes arylation; HECK REACTION; PALLADIUM CATALYSTS; ARYL CHLORIDES; HYDROGENATION; ADSORPTION; CHEMISTRY; SUZUKI;
D O I
10.1016/j.catcom.2012.02.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new pincer-type ligand containing Pd(II) was immobilized on a modified bentonite. The material was evaluated as catalyst in the arylation of iodobenzene and several alkenes under room conditions. The catalyst combines high activity and selectivity, and can be reused three times with no observed deactivation. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:82 / 85
页数:4
相关论文
共 21 条
[1]   The heck reaction as a sharpening stone of palladium catalysis [J].
Beletskaya, IP ;
Cheprakov, AV .
CHEMICAL REVIEWS, 2000, 100 (08) :3009-3066
[2]   Palladium(II) containing hydrotalcite as an efficient heterogeneous catalyst for Heck reaction [J].
Bennur, TH ;
Ramani, A ;
Bal, R ;
Chanda, BM ;
Sivasanker, S .
CATALYSIS COMMUNICATIONS, 2002, 3 (10) :493-496
[3]   Bis(pyrimidine)-based palladium catalysts: synthesis, X-ray structure and applications in Heck-, Suzuki-, Sonogashira-Hagihara couplings and amination reactions [J].
Buchmeiser, MR ;
Schareina, T ;
Kempe, R ;
Wurst, K .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 634 (01) :39-46
[4]   XAFS study of tin modification of supported palladium catalyst for 1,3-butadiene hydrogenation in the presence of 1-butene [J].
Choi, SH ;
Lee, JS .
JOURNAL OF CATALYSIS, 2000, 193 (02) :176-185
[5]   Layered double hydroxide supported nanopalladium catalyst for Heck-, Suzuki-, Sonogashira-, and Stille-type coupling reactions of chloroarenes [J].
Choudary, BM ;
Madhi, S ;
Chowdari, NS ;
Kantam, ML ;
Sreedhar, B .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (47) :14127-14136
[6]   Basic zeolites containing palladium as bifunctional heterogeneous catalysts for the Heck reaction [J].
Corma, A ;
García, H ;
Leyva, A ;
Primo, A .
APPLIED CATALYSIS A-GENERAL, 2003, 247 (01) :41-49
[7]   Polyvinyl chloride-polyethylene-polyamine supported palladium complexes as high efficient and recyclable catalysts for Heck reaction [J].
Cui, YC ;
Zhang, L .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 237 (1-2) :120-125
[8]   High-turnover palladium catalysts in cross-coupling and Heck chemistry: A critical overview [J].
Farina, V .
ADVANCED SYNTHESIS & CATALYSIS, 2004, 346 (13-15) :1553-1582
[9]   Free-energy of adsorption of a cationic surfactant onto Na-bentonite (Iran): inspection of adsorption layer by X-ray spectroscopy [J].
Ghiaci, M ;
Kalbasi, RJ ;
Khani, H ;
Abbaspur, A ;
Shariatmadari, H .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2004, 36 (08) :707-713
[10]   Preparation of Pd (0) and Pd (II) nanotubes and nanoparticles on modified bentonite and their catalytic activity in oxidation of ethyl benzene to acetophenone [J].
Ghiaci, M. ;
Sadeghi, Z. ;
Sedaghat, M. E. ;
Karimi-Maleh, H. ;
Safaei-Ghomi, J. ;
Gil, A. .
APPLIED CATALYSIS A-GENERAL, 2010, 381 (1-2) :121-131