Synthesis, crystal structure and Hirshfeld surface of bis(2-aminopyridinium) hexachloridostannate(IV)

被引：3

作者：

Ghallab, Rochdi ^{[1
]}

Boutebdja, Mehdi ^{[1
]}

Denes, George ^{[2
]}

Merazig, Hocine ^{[1
]}

机构：

[1] Univ Constantine 1, Environm Mol & Struct Chem Res Unit, Constantine 25000, Algeria

[2] Concordia Univ, Dept Chem & Biochem, Lab Solid State Chem & Mossbauer Spect, 7141 St West, Montreal, PQ H4B 1R6, Canada

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2020年 / 76卷

关键词：

Zero-dimensional hybrid perovskite; aminopyridine; Hirshfeld surface; Raman spectroscopy; crystal structure; VIBRATIONAL-SPECTRA; MOLECULES;

D O I：

10.1107/S205698902000941X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title molecular salt, (C5H7N2)(2)[SnCl6], the cation is protonated at the pyridine N atom and the complete dianion is generated by a crystallographic centre of symmetry. In the crystal, N-H center dot center dot center dot Cl hydrogen bonds link the components into a three-dimensional network built up from the stacking of alternate cationic and anionic layers. The nature of the intermolecular interactions has been analysed in terms of the Hirshfeld surfaces of the cations and the anions. The thermal behaviour and the Raman spectrum of the title compound are reported.

引用

页码：1279 / +

页数：8

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