Superheated liquid and supercritical denatured ethanol extraction of antioxidants from Crimson red grape stems

被引:11
作者
Wenzel, Jonathan [1 ]
Samaniego, Cheryl Storer [1 ]
Wang, Lihua [1 ]
Nelson, La'Shyla [1 ]
Ketchum, Korrine [1 ]
Ammerman, Michelle [1 ]
Zand, Ali [1 ]
机构
[1] Kettering Univ, 1700 Univ Ave, Flint, MI 48504 USA
关键词
Antioxidant activity; Crimson seedless grape; FRAP assay; grape stem extracts; supercritical ethanol extraction; superheated liquid ethanol extraction; TPC; VITIS-VINIFERA L; PHENOLIC ANTIOXIDANTS; CARBON-DIOXIDE; BY-PRODUCTS; DIELECTRIC-CONSTANT; POMACE EXTRACTS; FRAP ASSAY; RESIDUES; WINE; DISTILLATION;
D O I
10.1002/fsn3.246
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
Grapes are widely known for health benefits due to their antioxidant content. In wine production, grape stems are often discarded, though they has a higher content of antioxidants than the juice. The effectiveness of using an environmentally friendly solvent, ethanol, as a superheated liquid and supercritical fluid to extract antioxidant compounds from grape stems of organically grown Crimson Seedless grapes was evaluated. The Ferric Reducing Ability of Plasma (FRAP) assay and the Total Phenolic Content (TPC), or Folin-Ciocalteu assay, were used to quantify the antioxidant power of grape stem extracts. The extractions were performed at temperatures between 160 degrees C and 300 degrees C at constant density. It was found that the optimal extraction temperature was 204 degrees C, at superheated liquid conditions, with a FRAP value of 0.670 mmol Trolox Equivalent/g of dry grape stem. The FRAP values were higher than other studies that extracted antioxidants from grape stems using single-pass batch extraction.
引用
收藏
页码:569 / 576
页数:8
相关论文
共 38 条
[11]   Phenolic composition and antioxidant activity in grapevine parts and berries (Vitis vinifera L.) cv. Kishmish Chornyi (Sharad Seedless) during maturation [J].
Doshi, Pooja ;
Adsule, Pandurang ;
Banerjee, Kaushik .
INTERNATIONAL JOURNAL OF FOOD SCIENCE AND TECHNOLOGY, 2006, 41 :1-9
[12]   Changes in the phytoalexin content of various Vitis spp. in response to ultraviolet C elicitation [J].
Douillet-Breuil, AC ;
Jeandet, P ;
Adrian, M ;
Bessis, N .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1999, 47 (10) :4456-4461
[13]  
Folin O, 1927, J BIOL CHEM, V73, P627
[14]   Supercritical Fluid Extraction of Phenolic Compounds and Antioxidants from Grape (Vitis labrusca B.) Seeds [J].
Ghafoor, Kashif ;
AL-Juhaimi, Fahad Y. ;
Choi, Yong Hee .
PLANT FOODS FOR HUMAN NUTRITION, 2012, 67 (04) :407-414
[15]   Antioxidant activities of peel, pulp and seed fractions of common fruits as determined by FRAP assay [J].
Guo, CJ ;
Yang, JJ ;
Wei, JY ;
Li, YF ;
Xu, J ;
Jiang, YG .
NUTRITION RESEARCH, 2003, 23 (12) :1719-1726
[16]   Synergic effect of grape seed extract with amphotericin B against disseminated candidiasis due to Candida albicans [J].
Han, Yongmoon .
PHYTOMEDICINE, 2007, 14 (11) :733-738
[17]   Polyphenolic profile, antioxidant properties and antimicrobial activity of grape skin extracts of 14 Vitis vinifera varieties grown in Dalmatia (Croatia) [J].
Katalinic, Visnja ;
Mozina, Sonja Smole ;
Skroza, Danijela ;
Generalic, Ivana ;
Abramovic, Helena ;
Milos, Mladen ;
Ljubenkov, Ivica ;
Piskernik, Sasa ;
Pezo, Ivan ;
Terpinc, Petra ;
Boban, Mladen .
FOOD CHEMISTRY, 2010, 119 (02) :715-723
[18]   The dielectric constant of carbon dioxide as a function of temperature and density [J].
Keyes, FG ;
Kirkwood, JG .
PHYSICAL REVIEW, 1930, 36 (04) :0754-0761
[19]   Solubilities of 4-phenyltoluene, phenylboric acid, biphenyl, and iodobenzene in carbon dioxide from measurements of the relative permittivity [J].
Leeke, G ;
Santos, R ;
Al-Duri, B ;
Seville, J ;
Smith, C ;
Holmes, AB .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (04) :1370-1374
[20]   Dietary fibre content and antioxidant activity of Manto Negro red grape (Vitis vinifera):: pomace and stem [J].
Llobera, Antonia ;
Canellas, Jaime .
FOOD CHEMISTRY, 2007, 101 (02) :659-666