CuCl2-Mediated Hydroxylation of 2,3-Dimethyl-5-hydroxy-6-aminopyrimidine-4(3H)-one with Molecular Oxygen in Aqueous and Non-Aqueous Solutions

被引：1
|
作者：
Mishinkin, V. Yu. [1 ]
Grabovskii, S. A. [1 ]
Kabal'nova, N. N. [1 ]
Murinov, Yu. I. [1 ]
机构：
[1] Russian Acad Sci, Ufa Fed Res Ctr, Ufa Inst Chem, Pr Oktyabrya 69, Ufa 450054, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2019年 / 89卷 / 03期
关键词：
molecular oxygen; 2,3-dimethyl-5-hydroxy-6-aminopyrimidine-4(3H)-one; copper(II) ions; hydroxylation; COMPLEXES;
D O I：
10.1134/S107036321903006X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The catalytic hydroxylation of 2,3-dimethyl-5-hydroxy-6-aminopyrimidine-4(3H)-one in an aqueous solution in the presence of copper(II) ions and oxygen proceeds with the formation of 2,3-dimethyl-5,5,6-trihydroxy-6-aminopyrimidine-4-(3H)-one.
引用
收藏
页码：405 / 408
页数：4
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