Synthesis and Characterization of Nanostructured Copper Zinc Tin Sulphide (CZTS) for Humidity Sensing Applications

被引:33
作者
Maurya, Dheeraj Kumar [1 ]
Sikarwar, Samiksha [2 ]
Chaudhary, Priyanka [2 ]
Angaiah, Subramania [1 ]
Yadav, Bal Chandra [2 ]
机构
[1] Pondicherry Univ, Electrochem Energy Res Lab, Ctr Nanosci & Technol, Pondicherry 605014, India
[2] Babasaheb Bhimrao Ambedkar Univ, Dept Phys, Nanomat & Sensors Res Lab, Lucknow 226025, Uttar Pradesh, India
关键词
CZTS (Cu2ZnSnS4); humidity sensing; optical humidity sensing; RELATIVE-HUMIDITY; SENSORS; TEMPERATURE;
D O I
10.1109/JSEN.2018.2890309
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Copper zinc tin sulphide (CZTS) microsphere comprising thin nano sheets with high porosity and the wide surface area was developed via the surfactant-assisted hydrothermal method and was further characterized using XRD, FESEM, and TEM revealing its crystalline nature, efficient morphology, and internal structural, respectively. The band gap of CZTS is found to be 1.8 eV owing minimum crystallite size and the average crystallite size of 13 and 34 nm, respectively. The absorption analysis of CZTS was done using UV-Vis, FTIR, and Raman spectroscopy. Finally, the humidity sensing capability of the material was enquired using both the electrical and optical modes. Electrical mode gave an excellent sensitivity of 10.77 Omega/%RH with the fast response and recovery times of 7.4 and 57 s, respectively, whereas optical mode gave a sensitivity of similar to 1.051 mu W/%RH with the response and recovery times of 46 and 80 s, respectively.
引用
收藏
页码:2837 / 2846
页数:10
相关论文
共 37 条
[1]   Relative humidity sensor based on SMS fiber structure with polyvinyl alcohol coating [J].
An, Jiali ;
Zhao, Yu ;
Jin, Yongxing ;
Shen, Changyu .
OPTIK, 2013, 124 (23) :6178-6181
[2]   A heating-up method for the synthesis of pure phase kesterite Cu2ZnSnS4 nanocrystals using a simple coordinating sulphur precursor [J].
An, Ping ;
Liang, Zhurong ;
Xu, Xueqing ;
Wang, Xin ;
Jin, Hu ;
Wang, Nan ;
Wang, Junxia ;
Zhu, Furong .
RSC ADVANCES, 2015, 5 (09) :6879-6885
[3]   Synthesis and characterization of copper (II) nitrate polyacrylamide & its application as opto-electronic humidity sensor [J].
Chaudhary, Priyanka ;
Sikarwar, Samiksha ;
Yadav, B. C. ;
Dzhardimalieva, G. I. ;
Golubeva, Nina D. ;
Uflyand, Igor E. .
SENSORS AND ACTUATORS A-PHYSICAL, 2017, 263 :415-422
[4]   Humidity sensors: A review of materials and mechanisms [J].
Chen, Z ;
Lu, C .
SENSOR LETTERS, 2005, 3 (04) :274-295
[5]   Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte [J].
Cheng, Eric Jianfeng ;
Sharafi, Asma ;
Sakamoto, Jeff .
ELECTROCHIMICA ACTA, 2017, 223 :85-91
[6]   BODY TEMPERATURE STUDIES IN ANESTHETIZED MAN - EFFECT OF ENVIRONMENTAL TEMPERATURE, HUMIDITY, AND ANESTHESIA SYSTEM [J].
CLARK, RE ;
ORKIN, LR ;
ROVENSTINE, EA .
JAMA-JOURNAL OF THE AMERICAN MEDICAL ASSOCIATION, 1954, 154 (04) :311-319
[7]   Kesterite thin films for photovoltaics: a review [J].
Delbos, S. .
EPJ PHOTOVOLTAICS, 2012, 3
[8]   Humidity Sensors Principle, Mechanism, and Fabrication Technologies: A Comprehensive Review [J].
Farahani, Hamid ;
Wagiran, Rahman ;
Hamidon, Mohd Nizar .
SENSORS, 2014, 14 (05) :7881-7939
[9]   Gas sensing properties of hydrothermally grown ZnO nanorods with different aspect ratios [J].
Gurav, K. V. ;
Gang, M. G. ;
Shin, S. W. ;
Patil, U. M. ;
Deshmukh, P. R. ;
Agawane, G. L. ;
Suryawanshi, M. P. ;
Pawar, S. M. ;
Patil, P. S. ;
Lokhande, C. D. ;
Kim, J. H. .
SENSORS AND ACTUATORS B-CHEMICAL, 2014, 190 :439-445
[10]  
Jones F. R., 2014, RESPONSE AEROSPACE C