Encapsulation of small organic molecules by a self-assembled molecular capsule through charged hydrogen bonding interaction

被引：51

作者：

Lee, SB ^{[1
]}

Hong, JI ^{[1
]}

机构：

[1] SEOUL NATL UNIV,DEPT CHEM,SEOUL 151742,SOUTH KOREA

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 47期

关键词：

D O I：

10.1016/0040-4039(96)01950-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Self-assembled heterodimeric molecular capsule based on the charged hydrogen bonding interaction between two different CTV monomers (1 and 2) was developed. The formation of the molecular capsule was confirmed by inclusion phenomena of complementary neutral guests in DMSO-d(6). The encapsulated TMS was released by prolonged heating or pH adjustment. Molecular modeling and intermolecular NOEs suggested the three-dimensional structure of the termolecular inclusion complex. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：8501 / 8504

页数：4

共 20 条

[1] Alberts B., 2017, Molecular biology of the cell
[2] VAN DER WAALS VOLUMES + RADII
BONDI, A
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) : 441 - +
[3] ENCAPSULATION OF METHANE AND OTHER SMALL MOLECULES IN A SELF-ASSEMBLING SUPERSTRUCTURE
BRANDA, N
WYLER, R
REBEK, J
[J]. SCIENCE, 1994, 263 (5151) : 1267 - 1268
[4] CONTROL OF SELF-ASSEMBLY AND REVERSIBLE ENCAPSULATION OF XENON IN A SELF-ASSEMBLING DIMER BY ACID-BASE CHEMISTRY
BRANDA, N
GROTZFELD, RM
VALDES, C
REBEK, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (01) : 85 - 88
[5] CYCLOTRIVERATRYLENES AND CRYPTOPHANES
COLLET, A
[J]. TETRAHEDRON, 1987, 43 (24) : 5725 - 5759
[6] COLLET A, 1993, TOP CURR CHEM, V165, P103
[7] SELF-ASSEMBLY OF 10 MOLECULES INTO NANOMETER-SIZED ORGANIC HOST FRAMEWORKS
FUJITA, M
OGURO, D
MIYAZAWA, M
OKA, H
YAMAGUCHI, K
OGURA, K
[J]. NATURE, 1995, 378 (6556) : 469 - 471
[8] Reversible encapsulation of disc-shaped guests by a synthetic, self-assembled host
Grotzfeld, RM
Branda, N
Rebek, J
[J]. SCIENCE, 1996, 271 (5248) : 487 - 489
[9] FROM MACROMOLECULES TO BIOLOGICAL ASSEMBLIES (NOBEL LECTURE)
KLUG, A
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1983, 22 (08): : 565 - 582
[10] SELF-ASSEMBLED MOLECULAR CAPSULE BASED ON THE HYDROGEN-BONDING INTERACTION BETWEEN 2 DIFFERENT CALIX[4]ARENES
KOH, K
ARAKI, K
SHINKAI, S
[J]. TETRAHEDRON LETTERS, 1994, 35 (44) : 8255 - 8258

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