Crystal structure of an unsymmetrical Schiff base, immobilization of its cobalt and manganese complexes on a silica support, and catalytic studies

被引：12

作者：

Durak, Damla ^{[1
]}

Delikanli, Anil ^{[1
]}

Demetgul, Cahit ^{[2
]}

Kani, Ibrahim ^{[3
]}

Serin, Selahattin ^{[1
]}

机构：

[1] Cukurova Univ, Dept Chem, Fac Sci & Letters, TR-01330 Adana, Turkey

[2] Mustafa Kemal Univ, Dept Chem, Fac Sci & Letters, TR-31040 Antakya, Turkey

[3] Anadolu Univ, Dept Chem, Fac Sci, TR-26470 Eskisehir, Turkey

来源：

TRANSITION METAL CHEMISTRY | 2013年 / 38卷 / 02期

关键词：

ANTIMICROBIAL ACTIVITY; METAL-COMPLEXES; LIGANDS; EPOXIDATION; COPPER; OLEFINS; ZINC;

D O I：

10.1007/s11243-012-9678-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An unsymmetrical tetradentate Schiff base (H2L) was synthesized by the reaction of 3-methoxysalicylaldehyde, o-phenylenediamine, and salicylaldehyde in EtOH. H2L was characterized by single-crystallographic X-ray analysis. Its Co(II) and Mn(III) complexes ([CoL] and [MnLCl]) were prepared and immobilized on 3-aminopropyltriethoxysilane functionalized silica gel. The immobilized materials were found to be efficient catalysts for epoxidation of styrene in the presence of tert-BuOOH in acetonitrile at 40 A degrees C. The catalysts can be reused several times without significant loss of performance.

引用

页码：199 / 206

页数：8

共 31 条

[1] [Anonymous], 2015, Acta Crystallogr., V71, P3
[2] [Anonymous], 2007, BRUK APEX2 VERS 7 23
[3] Periodic mesoporous organosilica incorporating a catalytically active vanadyl Schiff base complex in the framework
Baleizao, C
Gigante, B
Das, D
Alvaro, M
Garcia, H
Corma, A
[J]. JOURNAL OF CATALYSIS, 2004, 223 (01) : 106 - 113
[4] Binding of transition metal ions [cobalt, copper, nickel and zinc] with furanyl-, thiophenyl-, pyrrolyl-, salicylyl- and pyridyl-derived cephalexins as potent antibacterial agents
Chohan, ZH
Pervez, H
Khan, KM
Rauf, A
Supuran, CT
[J]. JOURNAL OF ENZYME INHIBITION AND MEDICINAL CHEMISTRY, 2004, 19 (01) : 51 - 56
[5] Post-synthesis organo-sylanation of mesostructured FSM-16 for chiral Mn(III) salen catalyst anchoring
Das, Pankaj
Silva, Ana Rosa
Carvalho, Ana P.
Pires, Joao
Freire, Cristina
[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2008, 329 (03) : 190 - 197
[6] Synthesis of a rhodium(I) carbonyl complex with a chiral aminodiphosphine ligand and its immobilization onto aminopropyl functionalized silica gel
Das, Pankaj
Borah, Malabika
Sarmah, Chandan
Gogoi, Pradip K.
Alekseenko, Lidia M.
Orlyk, Svetlana M.
[J]. JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (07) : 1107 - 1117
[7] Ordered porous materials for emerging applications
Davis, ME
[J]. NATURE, 2002, 417 (6891) : 813 - 821
[8] Demetgul C, 2008, DES MON POLYM, V565, P11
[9] Synthesis, characterization, and biological properties of Ni(II), Co(II), and Cu(II) complexes of Schiff bases derived from 4-aminobenzylamine
Demetgul, Cahit
Karakaplan, Mueruevvet
Serin, Selahattin
Digrak, Metin
[J]. JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (21) : 3544 - 3551
[10] Deshmukh PS, 2010, WORLD APPL SCI J, V9, P1301

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