[Cu2(μ-Me2N-ba)2bn)I]n, 1D coordination polymer of copper(I) iodide: synthesis, characterization, and crystal structure

被引：9

作者：

Khalaji, Aliakbar Dehno ^{[1
]}

Jafari, Khadijeh ^{[2
]}

Bahramian, Bahram ^{[2
]}

Fejfarova, Karla ^{[3
]}

Dusek, Michal ^{[3
]}

机构：

[1] Golestan Univ, Fac Sci, Dept Chem, Gorgan, Iran

[2] Shahrood Univ Technol, Coll Chem, Shahrood, Iran

[3] ASCR Vvi, Inst Phys, Prague 18221 8, Czech Republic

来源：

MONATSHEFTE FUR CHEMIE | 2013年 / 144卷 / 11期

关键词：

One-dimensional; Copper(I) iodide; Schiff-base; Single-crystal; SCHIFF-BASE; COMPLEXES; LIGANDS; THIOCYANATE; POLYNUCLEAR;

D O I：

10.1007/s00706-013-1039-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new one-dimensional coordination polymer of copper(I) iodide [Cu((mu (N,N')-Me2N-ba)(2)bn)I](n), with the bidentate Schiff-base ligand N,N'-bis(4-dimethylaminobenzylidene)butane-1,4-diamine, (Me2N-ba)(2)bn, containing a flexible spacer (=N-C-C-C-C-N=) has been synthesized and characterized by elemental analyses, C-13 and H-1 NMR, FT-IR, and thermal analysis. Its molecular structure has been determined by single-crystal X-ray diffraction. The copper(I) ion is coordinated in a distorted trigonal planar geometry by two N atoms of the symmetry related Schiff-base ligands and one I atom. The Schiff-base ligand adopts an E,E conformation and acts as a bis-monodentate bridging ligand (mu (N,N')), thus forming the 1D-chain copper(I) iodide coordination polymer.

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页码：1621 / 1626

页数：6

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