Superelastic percolation network of polyacrylamide (PAAm)-kappa carrageenan (κC) composite

被引:12
作者
Evingur, G. Akin [1 ]
Pekcan, O. [2 ]
机构
[1] Piri Reis Univ, TR-34940 Istanbul, Turkey
[2] Kadir Has Univ, TR-34083 Istanbul, Turkey
关键词
Universality; Elasticity; Acrylamide; Kappa carrageenan (kappa C); Superelastic percolation network; MECHANICAL-PROPERTIES; ELASTIC NETWORKS; HYDROGELS;
D O I
10.1007/s10570-013-9903-9
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
The elasticity of the polyacrylamide (PAAm)-kappa carrageenan (kappa C) composite was determined as a function of (w/v-%) kappa C content at 40 A degrees C. The gel composites studied contained various percentages (w/v-%) of kappa C. The elasticity of the swollen PAAm-kappa C composite was characterized by using the tensile testing technique. This study investigated the elasticity and the percolation threshold of PAAm-kappa C composite as a function of kappa C content. It is understood that the compressive elastic modulus decreases up to 1 (w/v-%) of kappa C and then increases at contents above 1(w/v-%) of kappa C. The critical exponent of elasticity y was determined between 1 and 1.6 (w/v-%) of kappa C and found to be 0.68. The observed elastic percolation threshold is consistent with the suggested values of the superelastic percolation network.
引用
收藏
页码:1145 / 1151
页数:7
相关论文
共 22 条
[1]   Universal behaviour of gel formation from acrylamide-carrageenan mixture around the gel point:: A fluorescence study [J].
Aktas, Demet Kaya ;
Evingur, Gulsen Akin ;
Pekcan, Onder .
JOURNAL OF BIOMOLECULAR STRUCTURE & DYNAMICS, 2006, 24 (01) :83-90
[2]  
[Anonymous], 1994, Applications of Percolation Theory
[3]   Mechanical properties of hydrogels and their experimental determination [J].
Anseth, KS ;
Bowman, CN ;
BrannonPeppas, L .
BIOMATERIALS, 1996, 17 (17) :1647-1657
[4]   MECHANICS OF DISORDERED SOLIDS .1. PERCOLATION ON ELASTIC NETWORKS WITH CENTRAL FORCES [J].
ARBABI, S ;
SAHIMI, M .
PHYSICAL REVIEW B, 1993, 47 (02) :695-702
[5]   PERCOLATION THEORY AND ITS APPLICATION TO GROUNDWATER HYDROLOGY [J].
BERKOWITZ, B ;
BALBERG, I .
WATER RESOURCES RESEARCH, 1993, 29 (04) :775-794
[6]   Combining protein micro-phase separation and protein-polysaccharide segregative phase separation to produce gel structures [J].
Cakir, Esra ;
Foegeding, E. Allen .
FOOD HYDROCOLLOIDS, 2011, 25 (06) :1538-1546
[7]   DYNAMICS OF NEAR-CRITICAL POLYMER GELS [J].
COLBY, RH ;
GILLMOR, JR ;
RUBINSTEIN, M .
PHYSICAL REVIEW E, 1993, 48 (05) :3712-3716
[8]  
DEGENNES PG, 1976, J PHYS LETT-PARIS, V37, pL1, DOI 10.1051/jphyslet:019760037010100
[9]   CRITICAL PHENOMENA AND TRANSITIONS IN SWOLLEN POLYMER NETWORKS AND IN LINEAR MACROMOLECULES [J].
ERMAN, B ;
FLORY, PJ .
MACROMOLECULES, 1986, 19 (09) :2342-2353
[10]   Temperature Effect on the Swelling of PAAm-κ-carrageenan Composites [J].
Evingur, G. Akin ;
Pekcan, O. .
JOURNAL OF APPLIED POLYMER SCIENCE, 2012, 123 (03) :1746-1754