Recombination and redox couples in dye-sensitized solar cells

被引：96

作者：

Ondersma, Jesse W. ^{[1
]}

Hamann, Thomas W. ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2013年 / 257卷 / 9-10期

关键词：

Solar energy; Electron transfer; Redox shuttles; Dye-sensitized; TRANSFER RATE CONSTANTS; INTENSITY-MODULATED PHOTOVOLTAGE; NANOCRYSTALLINE TITANIUM-DIOXIDE; INTERFACIAL ELECTRON-TRANSFER; OPEN-CIRCUIT VOLTAGE; CHARGE-TRANSFER; PHOTOELECTROCHEMICAL CELL; PERFORMANCE ENHANCEMENT; TIO2; FILMS; TIN OXIDE;

D O I：

10.1016/j.ccr.2012.09.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this review we describe the importance of interfacial electron-transfer reactions from nanoparticle TiO2 films to redox shuttles (i.e. recombination) in the context of dye-sensitized solar cells. The focus is on the use of outersphere redox couples to perform systematic investigations of recombination reactions. A primary example is a system of cobalt(III/II) tris-bipyridyl complexes. The result of these studies allowed for the development of a relatively simple model to predict the efficiency of DSSCs as a function of redox couple potential and reorganization energy. Results from the new redox systems, which were motivated by the model results, are also presented. In addition, methods of controlling recombination which can lead to high-efficiency solar cells are discussed. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：1533 / 1543

页数：11

共 89 条

[21] Dye-Sensitized Solar Cells: Driving-Force Effects on Electron Recombination Dynamics with Cobalt-Based Shuttles [J].

DeVries, Michael J. ;

Pellin, Michael J. ;

Hupp, Joseph T. .

LANGMUIR, 2010, 26 (11) :9082-9087

[22] A global "Manhattan project" for the energy crisis [J].

Eaglesham, DJ .

MRS BULLETIN, 2005, 30 (12) :923-923

[23] The origin of slow electron recombination processes in dye-sensitized solar cells with alumina barrier coatings [J].

Fabregat-Santiago, F ;

García-Cañadas, J ;

Palomares, E ;

Clifford, JN ;

Haque, SA ;

Durrant, JR ;

Garcia-Belmonte, G ;

Bisquert, J .

JOURNAL OF APPLIED PHYSICS, 2004, 96 (11) :6903-6907

[24] Cyclic voltammetry studies of nanoporous semiconductors.: Capacitive and reactive properties of nanocrystalline TiO2 electrodes in aqueous electrolyte [J].

Fabregat-Santiago, F ;

Mora-Seró, I ;

Garcia-Belmonte, G ;

Bisquert, J .

JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (03) :758-768

[25] Electron Transport and Recombination in Solid-State Dye Solar Cell with Spiro-OMeTAD as Hole Conductor [J].

Fabregat-Santiago, Francisco ;

Bisquert, Juan ;

Cevey, Le ;

Chen, Peter ;

Wang, Mingkui ;

Zakeeruddin, Shaik M. ;

Graetzel, Michael .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (02) :558-562

[26] Effects of Driving Forces for Recombination and Regeneration on the Photovoltaic Performance of Dye-Sensitized Solar Cells using Cobalt Polypyridine Redox Couples [J].

Feldt, Sandra M. ;

Wang, Gang ;

Boschloo, Gerrit ;

Hagfeldt, Anders .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (43) :21500-21507

[27] Design of Organic Dyes and Cobalt Polypyridine Redox Mediators for High-Efficiency Dye-Sensitized Solar Cells [J].

Feldt, Sandra M. ;

Gibson, Elizabeth A. ;

Gabrielsson, Erik ;

Sun, Licheng ;

Boschloo, Gerrit ;

Hagfeldt, Anders .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (46) :16714-16724

[28] Thermally activated, inverted interfacial electron transfer kinetics: High driving force reactions between tin oxide nanoparticles and electrostatically-bound molecular reactants [J].

Gaal, DA ;

Hupp, JT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (44) :10956-10963

[29] SENSITIZATION OF CHARGE INJECTION INTO SEMICONDUCTORS WITH LARGE BAND GAP [J].

GERISCHE.H ;

MICHELBE.ME ;

REBENTRO.F ;

TRIBUTSC.H .

ELECTROCHIMICA ACTA, 1968, 13 (06) :1509-&

[30] ELECTROCHEMISTRY OF ZNO MONOCRYSTAL SPECTRAL SENSITIVITY [J].

GERISCHER, H ;

TRIBUTSCH, H .

BERICHTE DER BUNSEN-GESELLSCHAFT FUR PHYSIKALISCHE CHEMIE, 1968, 72 (03) :437-+

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