Recombination and redox couples in dye-sensitized solar cells

被引：96

作者：

Ondersma, Jesse W. ^{[1
]}

Hamann, Thomas W. ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2013年 / 257卷 / 9-10期

关键词：

Solar energy; Electron transfer; Redox shuttles; Dye-sensitized; TRANSFER RATE CONSTANTS; INTENSITY-MODULATED PHOTOVOLTAGE; NANOCRYSTALLINE TITANIUM-DIOXIDE; INTERFACIAL ELECTRON-TRANSFER; OPEN-CIRCUIT VOLTAGE; CHARGE-TRANSFER; PHOTOELECTROCHEMICAL CELL; PERFORMANCE ENHANCEMENT; TIO2; FILMS; TIN OXIDE;

D O I：

10.1016/j.ccr.2012.09.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this review we describe the importance of interfacial electron-transfer reactions from nanoparticle TiO2 films to redox shuttles (i.e. recombination) in the context of dye-sensitized solar cells. The focus is on the use of outersphere redox couples to perform systematic investigations of recombination reactions. A primary example is a system of cobalt(III/II) tris-bipyridyl complexes. The result of these studies allowed for the development of a relatively simple model to predict the efficiency of DSSCs as a function of redox couple potential and reorganization energy. Results from the new redox systems, which were motivated by the model results, are also presented. In addition, methods of controlling recombination which can lead to high-efficiency solar cells are discussed. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：1533 / 1543

页数：11

共 89 条

[1] The limiting role of iodide oxidation in cis-Os(dcb)2(CN)2/TiO2 photoelectrochemical cells [J].

Alebbi, M ;

Bignozzi, CA ;

Heimer, TA ;

Hasselmann, GM ;

Meyer, GJ .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (39) :7577-7581

[2] DESIGN OF ANTENNA-SENSITIZER POLYNUCLEAR COMPLEXES - SENSITIZATION OF TITANIUM-DIOXIDE WITH [RU(BPY)2(CN)2]2RU(BPY(COO)2)22- [J].

AMADELLI, R ;

ARGAZZI, R ;

BIGNOZZI, CA ;

SCANDOLA, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (20) :7099-7103

[3] Simultaneous Transient Absorption and Transient Electrical Measurements on Operating Dye-Sensitized Solar Cells: Elucidating the Intermediates in Iodide Oxidation [J].

Anderson, Assaf Y. ;

Barnes, Piers R. F. ;

Durrant, James R. ;

O'Regan, Brian C. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (04) :1953-1958

[4]

[Anonymous], 2005, FOLL WORKSH REP CAN

[5]

[Anonymous], 2011, Key world energy statistics

[6]

[Anonymous], 2012, RENEWABLE ENERGY SOU

[7] Engineering Organic Sensitizers for Iodine-Free Dye-Sensitized Solar Cells: Red-Shifted Current Response Concomitant with Attenuated Charge Recombination [J].

Bai, Yu ;

Zhang, Jing ;

Zhou, Difei ;

Wang, Yinghui ;

Zhang, Min ;

Wang, Peng .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (30) :11442-11445

[8] Determination of rate constants for charge transfer and the distribution of semiconductor and electrolyte electronic energy levels in dye-sensitized solar cells by open-circuit photovoltage decay method [J].

Bisquert, J ;

Zaban, A ;

Greenshtein, M ;

Mora-Seró, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (41) :13550-13559

[9] Interpretation of the time constants measured by kinetic techniques in nanostructured semiconductor electrodes and dye-sensitized solar cells [J].

Bisquert, J ;

Vikhrenko, VS .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (07) :2313-2322

[10] Analysis of the mechanisms of electron recombination in nanoporous TiO2 dye-sensitized solar cells.: Nonequilibrium steady-state statistics and interfacial electron transfer via surface states [J].

Bisquert, J ;

Zaban, A ;

Salvador, P .

JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (34) :8774-8782

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