One-dimensional structure of boron nitride on chromium (110) - a study of the growth of boron nitride by chemical vapour deposition of borazine

被引：42
作者：
Mueller, Frank [1 ,2 ]
Huefner, Stefan [2 ]
Sachdev, Hermann [1 ]
机构：
[1] Univ Saarland, Inst Anorgan Chem, Nat Wissenschaftlich Tech Fak Chem Pharm & Werkst, D-66041 Saarbrucken, Germany
[2] Univ Saarland, Inst Expt Phys, Nat Wissenschaftlich Tech Fak Phys & Mechatron 2, D-66041 Saarbrucken, Germany
来源：
SURFACE SCIENCE | 2008年 / 602卷 / 22期
关键词：
Boron nitride; Chromium; Low energy electron diffraction (LEED); X-ray photoelectron spectroscopy (XPS); X-ray photoelectron diffraction (XPD); Chemical vapour deposition (CVD);
D O I：
10.1016/j.susc.2008.06.037
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The nucleation and growth of boron nitride films on a chromium (110) surface by thermal decomposition of borazine (HBNH)(3) was investigated by low energy electron diffraction (LEED), X-ray photoelectron spectroscopy (XPS) and X-ray photoelectron diffraction (XPD). The boron nitride film forms a chemically non-uniform one-dimensional superstructure with short range order along the [1 (1) over bar0] direction and long range order along [001]. Moreover, the thermal stability of the resulting BN film was investigated and a chemical reaction with the substrate was observed leading to the formation of Cr-B- and Cr-N- bonds at the interface and indicating the onset of the formation of hard boride and nitride phases in the system CrB-N. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：3467 / 3476
页数：10
相关论文
共 40 条
[1]  
AKAISHI G, 1988, J MATER SCI LETT, V7, P548
[2]   Tunable self-assembly of one-dimensional nanostructures with orthogonal directions [J].
Allan, Milan P. ;
Berner, Simon ;
Corso, Martina ;
Greber, Thomas ;
Osterwalder, Juerg .
NANOSCALE RESEARCH LETTERS, 2007, 2 (02) :94-99
[3]   XPD and STM investigation of hexagonal boron nitride on Ni(111) [J].
Auwärter, W ;
Kreutz, TJ ;
Greber, T ;
Osterwalder, J .
SURFACE SCIENCE, 1999, 429 (1-3) :229-236
[4]   Synthesis of one monolayer of hexagonal boron nitride on Ni(111) from B-trichloroborazine (ClBNH)3 [J].
Auwärter, W ;
Suter, HU ;
Sachdev, H ;
Greber, T .
CHEMISTRY OF MATERIALS, 2004, 16 (02) :343-345
[5]   Defect lines and two-domain structure of hexagonal boron nitride films on Ni(111) [J].
Auwärter, W ;
Muntwiler, M ;
Osterwalder, J ;
Greber, T .
SURFACE SCIENCE, 2003, 545 (1-2) :L735-L740
[6]   Boron nitride nanomesh: Functionality from a corrugated monolayer [J].
Berner, Simon ;
Corso, Martina ;
Widmer, Roland ;
Groening, Oliver ;
Laskowski, Robert ;
Blaha, Peter ;
Schwarz, Karlheinz ;
Goriachko, Andrii ;
Over, Herbert ;
Gsell, Stefan ;
Schreck, Matthias ;
Sachdev, Hermann ;
Greber, Thomas ;
Osterwalder, Juerg .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (27) :5115-5119
[7]   h-BN on Pd(110):: a tunable system for self-assembled nanostructures? [J].
Corso, M ;
Greber, T ;
Osterwalder, J .
SURFACE SCIENCE, 2005, 577 (2-3) :L78-L84
[8]   Boron nitride nanomesh [J].
Corso, M ;
Auwärter, W ;
Muntwiler, M ;
Tamai, A ;
Greber, T ;
Osterwalder, J .
SCIENCE, 2004, 303 (5655) :217-220
[9]  
ERTL G, 1985, LOW ENERGY ELECTRONS, pCH9
[10]   Reconstructed pseudomorphic Co films on the Cr(110) surface [J].
Folsch, S ;
Helms, A ;
Steidinger, A ;
Rieder, KH .
PHYSICAL REVIEW B, 1998, 57 (08) :R4293-R4296
1234