Accelerated lithium-ion conduction in covalent organic frameworks

被引:52
作者
Sheng, Li [1 ]
Wang, Li [1 ]
Wang, Jianlong [1 ]
Xu, Hong [1 ]
He, Xiangming [1 ]
机构
[1] Tsinghua Univ, Inst Nucl & New Energy Technol, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
ELECTROLYTES; CRYSTALLINE; NANOSHEETS; DENSITY;
D O I
10.1039/d0cc04324a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We design a porous separator that consists of a covalent organic framework (COF), the ionic conductivity of which is 8 times higher than that of the most well-established separator of lithium-ion batteries. Moreover, the effective ionic conductivity is even higher than that of the corresponding pure liquid electrolyte.
引用
收藏
页码:10465 / 10468
页数:4
相关论文
共 24 条
[1]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[2]   Battery separators [J].
Arora, P ;
Zhang, ZM .
CHEMICAL REVIEWS, 2004, 104 (10) :4419-4462
[3]   Cationic Covalent Organic Framework Nanosheets for Fast Li-Ion Conduction [J].
Chen, Hongwei ;
Tu, Hangyu ;
Hu, Chenji ;
Liu, Yi ;
Dong, Derui ;
Sun, Yufei ;
Dai, Yafei ;
Wang, Senlin ;
Qian, Hao ;
Lin, Zhiyong ;
Chen, Liwei .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (03) :896-899
[4]   Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review [J].
Cheng, Xin-Bing ;
Zhang, Rui ;
Zhao, Chen-Zi ;
Zhang, Qiang .
CHEMICAL REVIEWS, 2017, 117 (15) :10403-10473
[5]   Promise and reality of post-lithium-ion batteries with high energy densities [J].
Choi, Jang Wook ;
Aurbach, Doron .
NATURE REVIEWS MATERIALS, 2016, 1 (04)
[6]   The atom, the molecule, and the covalent organic framework [J].
Diercks, Christian S. ;
Yaghi, Omar M. .
SCIENCE, 2017, 355 (6328)
[7]   Lithium-ion batteries with high charge rate capacity: Influence of the porous separator [J].
Djian, D. ;
Alloin, F. ;
Martinet, S. ;
Lignier, H. ;
Sanchez, J. Y. .
JOURNAL OF POWER SOURCES, 2007, 172 (01) :416-421
[8]   Synthesis and characterization of ZIF-69 membranes and separation for CO2/CO mixture [J].
Liu, Yunyang ;
Hu, Enping ;
Khan, Easir A. ;
Lai, Zhiping .
JOURNAL OF MEMBRANE SCIENCE, 2010, 353 (1-2) :36-40
[9]   Superior Charge Storage and Power Density of a Conducting Polymer-Modified Covalent Organic Framework [J].
Mulzer, Catherine R. ;
Shen, Luxi ;
Bisbey, Ryan P. ;
McKone, James R. ;
Zhang, Na ;
Abruna, Hector D. ;
Dichtel, William R. .
ACS CENTRAL SCIENCE, 2016, 2 (09) :667-673
[10]   Quenched solid density functional theory and pore size analysis of micro-mesoporous carbons [J].
Neimark, Alexander V. ;
Lin, Yangzheng ;
Ravikovitch, Peter I. ;
Thommes, Matthias .
CARBON, 2009, 47 (07) :1617-1628