Accelerated lithium-ion conduction in covalent organic frameworks

被引:48
作者
Sheng, Li [1 ]
Wang, Li [1 ]
Wang, Jianlong [1 ]
Xu, Hong [1 ]
He, Xiangming [1 ]
机构
[1] Tsinghua Univ, Inst Nucl & New Energy Technol, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
ELECTROLYTES; CRYSTALLINE; NANOSHEETS; DENSITY;
D O I
10.1039/d0cc04324a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We design a porous separator that consists of a covalent organic framework (COF), the ionic conductivity of which is 8 times higher than that of the most well-established separator of lithium-ion batteries. Moreover, the effective ionic conductivity is even higher than that of the corresponding pure liquid electrolyte.
引用
收藏
页码:10465 / 10468
页数:4
相关论文
共 24 条
  • [1] Building better batteries
    Armand, M.
    Tarascon, J. -M.
    [J]. NATURE, 2008, 451 (7179) : 652 - 657
  • [2] Battery separators
    Arora, P
    Zhang, ZM
    [J]. CHEMICAL REVIEWS, 2004, 104 (10) : 4419 - 4462
  • [3] Cationic Covalent Organic Framework Nanosheets for Fast Li-Ion Conduction
    Chen, Hongwei
    Tu, Hangyu
    Hu, Chenji
    Liu, Yi
    Dong, Derui
    Sun, Yufei
    Dai, Yafei
    Wang, Senlin
    Qian, Hao
    Lin, Zhiyong
    Chen, Liwei
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (03) : 896 - 899
  • [4] Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review
    Cheng, Xin-Bing
    Zhang, Rui
    Zhao, Chen-Zi
    Zhang, Qiang
    [J]. CHEMICAL REVIEWS, 2017, 117 (15) : 10403 - 10473
  • [5] Promise and reality of post-lithium-ion batteries with high energy densities
    Choi, Jang Wook
    Aurbach, Doron
    [J]. NATURE REVIEWS MATERIALS, 2016, 1 (04):
  • [6] The atom, the molecule, and the covalent organic framework
    Diercks, Christian S.
    Yaghi, Omar M.
    [J]. SCIENCE, 2017, 355 (6328)
  • [7] Lithium-ion batteries with high charge rate capacity: Influence of the porous separator
    Djian, D.
    Alloin, F.
    Martinet, S.
    Lignier, H.
    Sanchez, J. Y.
    [J]. JOURNAL OF POWER SOURCES, 2007, 172 (01) : 416 - 421
  • [8] Synthesis and characterization of ZIF-69 membranes and separation for CO2/CO mixture
    Liu, Yunyang
    Hu, Enping
    Khan, Easir A.
    Lai, Zhiping
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2010, 353 (1-2) : 36 - 40
  • [9] Superior Charge Storage and Power Density of a Conducting Polymer-Modified Covalent Organic Framework
    Mulzer, Catherine R.
    Shen, Luxi
    Bisbey, Ryan P.
    McKone, James R.
    Zhang, Na
    Abruna, Hector D.
    Dichtel, William R.
    [J]. ACS CENTRAL SCIENCE, 2016, 2 (09) : 667 - 673
  • [10] Quenched solid density functional theory and pore size analysis of micro-mesoporous carbons
    Neimark, Alexander V.
    Lin, Yangzheng
    Ravikovitch, Peter I.
    Thommes, Matthias
    [J]. CARBON, 2009, 47 (07) : 1617 - 1628