Grafted organic derivatives of kaolinite: I. Synthesis, chemical and rheological characterization

被引：89
作者：
Gardolinski, JEFC [1 ]
Lagaly, G [1 ]
机构：
[1] Univ Kiel, Inst Inorgan Chem, D-24098 Kiel, Germany
来源：
CLAY MINERALS | 2005年 / 40卷 / 04期
关键词：
dispersion; grafting; intercalation; kaolinite; rheology;
D O I：
10.1180/0009855054040190
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Several new interlayer-grafted derivatives of kaolinite were synthesized by esterification of inner-surface hydroxyl groups with alkanols, diols and glycol mono-ethers starting With the dimethyl sulphoxide intercalate. The derivatives were characterized by X-ray powder diffractometry, thermal analysis, Fourier transform infrared spectroscopy and transmission electron microscopy. The grafted molecules are arranged in monolayers between the kaolinite layers, with typical basal spacings of similar to 11.3 angstrom. Rheological studies of aqueous dispersions of the modified kaolinites revealed an exponential increase of the yield value and apparent viscosity with increasing alkyl chain length of the grafted molecules.
引用
收藏
页码：537 / 546
页数：10
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