Fe3O4 polyhedral nanoparticles with a high magnetization synthesized in mixed solvent ethylene glycol-water system

被引：95

作者：

Cao, Shao-Wen

Zhu, Ying-Jie ^{[1
]}

Chang, Jiang

机构：

[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2008年 / 32卷 / 09期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1039/b719436f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a solvothermal approach for the synthesis of high-magnetization Fe3O4 polyhedral nanoparticles in the ethylene glycol (EG)-H2O system. In this approach, ferric chloride (FeCl3.6H(2)O) is used as the iron source, and EG acts as both the solvent and reductant in the presence of sodium hydroxide (NaOH) and dodecylamine (DDA). The presence of deionized water plays an important role in the control over the size of Fe3O4 particles. The Fe3O4 particles prepared are well dispersed with single-crystal-like features, showing superparamagnetism with a high saturation magnetization close to that of bulk Fe3O4 (92 emu g(-1)). The stability of the Fe3O4 nanoparticles in deionized water is also investigated.

引用

页码：1526 / 1530

页数：5

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[1] Shape-controlled synthesis of colloidal platinum nanoparticles [J].

Ahmadi, TS ;

Wang, ZL ;

Green, TC ;

Henglein, A ;

ElSayed, MA .

SCIENCE, 1996, 272 (5270) :1924-1926

[2] Biomineralization - Naturally aligned nanocrystals [J].

Alivisatos, AP .

SCIENCE, 2000, 289 (5480) :736-737

[3] Perspectives on the physical chemistry of semiconductor nanocrystals [J].

Alivisatos, AP .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (31) :13226-13239

[4] Semiconductor clusters, nanocrystals, and quantum dots [J].

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[5] Aggregation-based crystal growth and microstructure development in natural iron oxyhydroxide biomineralization products [J].

Banfield, JF ;

Welch, SA ;

Zhang, HZ ;

Ebert, TT ;

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[6] Magnetic nanocomposite particles and hollow spheres constructed by a sequential layering approach [J].

Caruso, F ;

Spasova, M ;

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Caruso, RA .

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[7] Morphological control of Fe3O4 particles via glycothermal process [J].

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[9] Hydrothermal synthesis of monodisperse magnetite nanoparticles [J].

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Legare, P. ;

Bernhardt, P. ;

Leuvrey, C. ;

Rogez, G. .

CHEMISTRY OF MATERIALS, 2006, 18 (18) :4399-4404

[10] Monodisperse magnetic single-crystal ferrite microspheres [J].

Deng, H ;

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Chen, JP ;

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