Sn-based Chalcogenide Composite as a High-Capacity Anode Material for Lithium Rechargeable Batteries

被引：7
|
作者：
Lee, Youngmin [2 ]
Bae, Suk-Rok [1 ,3 ]
Park, Bong Je [4 ]
Shin, Dong Wook [2 ]
Chung, Woon Jin [1 ,3 ]
Kang, Yong-Mook [5 ]
机构：
[1] Kongju Natl Univ, Inst Rare Met, Cheonan 330717, Chungnam, South Korea
[2] Hanyang Univ, Div Mat Sci & Engn, Seoul 133791, South Korea
[3] Kongju Natl Univ, Div Adv Mat Engn, Cheonan 330717, Chungnam, South Korea
[4] ETRI, IT Convergence & Component Lab, Taejon 305350, South Korea
[5] Dongguk Univ, Dept Chem, Seoul 100715, South Korea
来源：
JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 2012年 / 95卷 / 07期
基金：
新加坡国家研究基金会;
关键词：
ION BATTERIES; ELECTROCHEMICAL PROPERTIES; TIN; GLASS; NANOPARTICLES; PERFORMANCE; NANOWIRES; OXIDE; SIZE;
D O I：
10.1111/j.1551-2916.2012.05194.x
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Sn-based chalcogenide composites (TCC) were synthesized as high-capacity anode materials. SnS formed within TCCs is an active center for Li-intercalation. Electrochemical cycling shows that the SnGeS matrix suppresses the volume expansion that can arise from alloying between Sn and Li as well as the grain growth associated with the low melting temperature of Sn. SnGeS complex phases in an amorphous state can contribute to the high capacity of Sn:GeS (6:4 m/m), possibly suppressing the agglomeration and pulverization of Sn.
引用
收藏
页码：2272 / 2276
页数：5
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