First example of the atom transfer radical polymerisation of an acidic monomer: direct synthesis of methacrylic acid copolymers in aqueous media

被引：180

作者：

Ashford, EJ ^{[1
]}

Naldi, V ^{[1
]}

O'Dell, R ^{[1
]}

Billingham, NC ^{[1
]}

Armes, SP ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 14期

关键词：

D O I：

10.1039/a903773j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sodium methacrylate is polymerised directly via atom transfer radical polymerisation (ATRP) in aqueous media using a poly(ethylene oxide)-based macro-initiator; the resulting poly(ethylene oxide-block-sodium methacrylate) copolymers were obtained in good yield and have narrow molecular weight distributions as evidenced by aqueous GPC.

引用

页码：1285 / 1286

页数：2

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