Raman and infrared spectroscopic study of turquoise minerals

被引：25

作者：

Cejka, Jiri ^{[1
,2
]}

Sejkora, Jiri ^{[1
]}

Macek, Ivo ^{[1
]}

Malikova, Radana ^{[1
]}

Wang, Lina ^{[2
]}

Scholz, Ricardo ^{[3
]}

Xi, Yunfei ^{[2
]}

Frost, Ray L. ^{[2
]}

机构：

[1] Natl Museum, Dept Mineral & Petrol, CZ-19300 Prague 9, Czech Republic

[2] Queensland Univ Technol, Fac Sci & Engn, Sch Chem Phys & Mech Engn, Brisbane, Qld 4001, Australia

[3] Univ Fed Ouro Preto, Sch Mines, Dept Geol, BR-3540000 Ouro Preto, MG, Brazil

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2015年 / 149卷

基金：

澳大利亚研究理事会;

关键词：

Turquoise; Phosphate; Hydroxyl ions; Raman spectroscopy; Infrared spectroscopy; CRYSTAL-STRUCTURE; PROVENANCE; MALACHITE; HYDROGEN; AZURITE;

D O I：

10.1016/j.saa.2015.04.029

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Raman and infrared spectra of three well-defined turquoise samples, CuAl6(PO4)(4)(OH)(8)center dot 4H(2)O, from Lavender Pit, Bisbee, Cochise county, Arizona; Kouroudaiko mine, Faleme river, Senegal and Lynch Station, Virginia were studied, interpreted and compared. Observed Raman and infrared bands were assigned to the stretching and bending vibrations of phosphate tetrahedra, water molecules and hydroxyl ions. Approximate O-H center dot center dot center dot O hydrogen bond lengths were inferred from the Raman and infrared spectra. No Raman and infrared bands attributable to the stretching and bending vibrations of (PO3OH)(2-) units were observed. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：173 / 182

页数：10

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