Tetrazole-Stabilized Gold Nanoparticles for Catalytic Applications

被引:11
作者
Guhrenz, Chris [1 ]
Wolf, Andre [1 ]
Adam, Marion [2 ]
Sonntag, Luisa [1 ,3 ]
Voitekhovich, Sergei V. [4 ]
Kaskel, Stefan [2 ]
Gaponik, Nikolai [1 ]
Eychmueller, Alexander [1 ,3 ]
机构
[1] Tech Univ Dresden, Phys Chem, Bergstr 66b, D-01062 Dresden, Germany
[2] Tech Univ Dresden, Inorgan Chem, Bergstr 66, D-01062 Dresden, Germany
[3] Tech Univ Dresden, Cluster Excellence Ctr Advancing Elect Dresden cf, Wurzburger Str 46, D-01187 Dresden, Germany
[4] Belarusian State Univ, Res Inst Phys Chem Problems, Leningradskaya 14, Minsk 220050, BELARUS
来源
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 2017年 / 231卷 / 01期
关键词
catalysis; CO oxidation; decomposition; gold; tetrazole; MEDICINAL CHEMISTRY; AU/TIO2; CATALYSTS; NANOCRYSTALS; SIZE; AU;
D O I
10.1515/zpch-2016-0879
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Herein, we report on a proof-of-concept application of tetrazole-stabilized Au nanoparticles (NPs) for CO oxidation. After impregnation of the support material TiO2 with the tetrazole-stabilized Au NPs (diameter < 5 nm), a thermal heat treatment under oxygen is used to remove the tetrazole from the NP surface. The resulting surfactant-free NPs are used in the CO oxidation and show enhanced catalytic activity in comparison to the untreated samples demonstrating the potential of tetrazole-stabilized NPs for various catalytic applications.
引用
收藏
页码:51 / 62
页数:12
相关论文
共 21 条
  • [1] THE CHEMISTRY OF THE TETRAZOLES
    BENSON, FR
    [J]. CHEMICAL REVIEWS, 1947, 41 (01) : 1 - 61
  • [2] Bond G. C., 1978, J CATAL, V55, P178
  • [3] Influence of Au Particle Size on Au/TiO2 Catalysts for CO Oxidation
    Du, Mingming
    Sun, Daohua
    Yang, Hongwei
    Huang, Jiale
    Jing, Xiaohan
    Odoom-Wubah, Tareque
    Wang, Haitao
    Jia, Lishan
    Li, Qingbiao
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (33) : 19150 - 19157
  • [4] When gold is not noble: Catalysis by nanoparticles
    Haruta, A
    [J]. CHEMICAL RECORD, 2003, 3 (02) : 75 - 87
  • [5] NOVEL GOLD CATALYSTS FOR THE OXIDATION OF CARBON-MONOXIDE AT A TEMPERATURE FAR BELOW 0-DEGREES-C
    HARUTA, M
    KOBAYASHI, T
    SANO, H
    YAMADA, N
    [J]. CHEMISTRY LETTERS, 1987, (02) : 405 - 408
  • [6] 5-substituted-1H-tetrazoles as carboxylic acid isosteres:: Medicinal chemistry and synthetic methods
    Herr, RJ
    [J]. BIOORGANIC & MEDICINAL CHEMISTRY, 2002, 10 (11) : 3379 - 3393
  • [7] VAPOR-PHASE HYDROCHLORINATION OF ACETYLENE - CORRELATION OF CATALYTIC ACTIVITY OF SUPPORTED METAL CHLORIDE CATALYSTS
    HUTCHINGS, GJ
    [J]. JOURNAL OF CATALYSIS, 1985, 96 (01) : 292 - 295
  • [8] Virtually Bare Nanocrystal Surfaces: Significantly Enhanced Electrical Transport in CuInSe2 and CuIn1-xGaxSe2 Thin Films upon Ligand Exchange with Thermally Degradable 1-Ethyl-5-Thiotetrazole
    Lauth, Jannika
    Marbach, Jakob
    Meyer, Andreas
    Dogan, Sedat
    Klinke, Christian
    Kornowski, Andreas
    Weller, Horst
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (08) : 1081 - 1088
  • [9] 3D Assembly of Semiconductor and Metal Nanocrystals: Hybrid CdTe/Au Structures with Controlled Content
    Lesnyak, Vladimir
    Wolf, Andre
    Dubavik, Aliaksei
    Borchardt, Lars
    Voitekhovich, Sergei V.
    Gaponik, Nikolai
    Kaskel, Stefan
    Eychmueller, Alexander
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (34) : 13413 - 13420
  • [10] Highly reproducible syntheses of active Au/TiO2 catalysts for CO oxidation by deposition-precipitation or impregnation
    Li, WC
    Comotti, M
    Schüth, F
    [J]. JOURNAL OF CATALYSIS, 2006, 237 (01) : 190 - 196