The influence of interface bonding on thermal transport through solid-liquid interfaces

被引:105
作者
Harikrishna, Hari [1 ]
Ducker, William A. [2 ]
Huxtable, Scott T. [3 ]
机构
[1] Virginia Tech, Dept Engn Sci & Mech, Blacksburg, VA 24061 USA
[2] Virginia Tech, Dept Chem Engn, Blacksburg, VA 24061 USA
[3] Virginia Tech, Dept Mech Engn, Blacksburg, VA 24061 USA
关键词
GOLD;
D O I
10.1063/1.4812749
中图分类号
O59 [应用物理学];
学科分类号
摘要
We use time-domain thermoreflectance to show that interface thermal conductance, G, is proportional to the thermodynamic work of adhesion between gold and water, W-SL, for a series of five alkane-thiol monolayers at the gold-water interface. W-SL is a measure of the bond strength across the solid-liquid interface. Differences in bond strength, and thus differences in W-SL, are achieved by varying the terminal group (omega-group) of the alkane-thiol monolayers on the gold. The interface thermal conductance values were in the range 60-190 MW m(-2) K-1, and the solid-liquid contact angles span from 25 degrees to 118 degrees. (C) 2013 AIP Publishing LLC.
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页数:4
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