Carbon nanotube-adsorbed electrospun nanofibrous membranes of nylon 6

被引:79
作者
Kim, HS [1 ]
Jin, HJ [1 ]
Myung, SJ [1 ]
Kang, MS [1 ]
Chin, IJ [1 ]
机构
[1] Inha Univ, Dept Polymer Sci & Engn, Inchon 402751, South Korea
关键词
composites; electrical conductivity; electrospinning; multiwalled carbon nanotubes; nanofibrous membrane; nylon;
D O I
10.1002/marc.200500617
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A simple and mass-producible method was developed to densely assemble multiwalled carbon nanotubes (MWNTs) onto electrospun nylon 6 nanofibrous membranes. The process consists of dispersing the acid-treated MWNTs in surfactant solutions or organic solvents, and dipping the nanofibrous membranes in the resulting dispersion for only 60 seconds, followed by the extraction of the surfactants in pure water and drying. The conductivity of the MWNT-adsorbed nanofibrous membranes ranges from 2.2 x 10(-2) to 1.5 x 10(-1) S (.) cm(-1), as determined by the four probe method, which implies that the MWNTs are adsorbed uniformly and densely along the nanofibrous membranes. Furthermore, the results suggest that there is a strong interaction between the acid-treated MWNTs and nylon 6. We also investigate the amount of MWNTs present in the membranes using thermoaravimetric analysis.
引用
收藏
页码:146 / 151
页数:6
相关论文
共 39 条
[1]  
Ajayan PM, 2000, ADV MATER, V12, P750, DOI 10.1002/(SICI)1521-4095(200005)12:10<750::AID-ADMA750>3.0.CO
[2]  
2-6
[3]   ALIGNED CARBON NANOTUBE ARRAYS FORMED BY CUTTING A POLYMER RESIN-NANOTUBE COMPOSITE [J].
AJAYAN, PM ;
STEPHAN, O ;
COLLIEX, C ;
TRAUTH, D .
SCIENCE, 1994, 265 (5176) :1212-1214
[4]   Carbon nanotubes - the route toward applications [J].
Baughman, RH ;
Zakhidov, AA ;
de Heer, WA .
SCIENCE, 2002, 297 (5582) :787-792
[5]   Solution properties of single-walled carbon nanotubes [J].
Chen, J ;
Hamon, MA ;
Hu, H ;
Chen, YS ;
Rao, AM ;
Eklund, PC ;
Haddon, RC .
SCIENCE, 1998, 282 (5386) :95-98
[6]   Non-destructive purification of multi-walled carbon nanotubes produced by catalyzed CVD [J].
Chen, XH ;
Chen, CS ;
Chen, Q ;
Cheng, FQ ;
Zhang, G ;
Chen, ZZ .
MATERIALS LETTERS, 2002, 57 (03) :734-738
[7]   Continuous carbon nanotube composite fibers: properties, potential applications, and problems [J].
Dalton, AB ;
Collins, S ;
Razal, J ;
Munoz, E ;
Ebron, VH ;
Kim, BG ;
Coleman, JN ;
Ferraris, JP ;
Baughman, RH .
JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (01) :1-3
[8]   Beaded nanofibers formed during electrospinning [J].
Fong, H ;
Chun, I ;
Reneker, DH .
POLYMER, 1999, 40 (16) :4585-4592
[9]  
Hamon MA, 1999, ADV MATER, V11, P834, DOI 10.1002/(SICI)1521-4095(199907)11:10<834::AID-ADMA834>3.0.CO
[10]  
2-R