Post-Modification of Organoiron Poly(alkynyl methacrylate)s with Dicobalt Hexacarbonyl

被引：9

作者：

Abd-El-Aziz, Alaa S. ^{[1
,2
]}

Winram, Diana J. ^{[2
]}

Shipman, Patrick O. ^{[2
]}

Rock, Christopher L. ^{[1
,2
]}

Vandel, Mason S. ^{[2
]}

Patrick, Brian O. ^{[3
]}

机构：

[1] Univ Prince Edward Isl, Dept Chem, Charlottetown, PE C1A 4P3, Canada

[2] Univ British Columbia, Dept Chem, Kelowna, BC, Canada

[3] Univ British Columbia, Dept Chem, Vancouver, BC, Canada

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2012年 / 213卷 / 20期

基金：

加拿大自然科学与工程研究理事会;

关键词：

alkynyl methacrylates; metal-containing polymers; organoiron; ORGANOMETALLIC POLYMERS; 2-FERROCENYLETHYL ACRYLATE; POLYMERIZATION; METALLOPOLYMERS; COMPLEXATION;

D O I：

10.1002/macp.201200405

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Radical polymerization of organoiron (alkynyl methacrylate)s afforded a series of organoiron poly(alkynyl methacrylate)s with the ability to coordinate dicobalt hexacarbonyl. The polymers were post-modified with dicobalt hexacarbonyl moieties through reaction with dicobaltoctacarbonyl. Gel permeation chromatography indicated that the polymers possessed weight average molecular weights between 17 800 Da and 33 900 Da with PDIs between 1.3 and 1.6. Thermal analysis revealed that the polymers possess glass transition temperatures between 78 and 138 degrees C.

引用

页码：2136 / 2145

页数：10

共 38 条

[1]

Abd-El-Aziz A. S., 2003, MACROMOLECULES CONTA, V2, P233

[2]

Abd-El-Aziz A.S., 2005, MACROMOLECULES CONTA, V6

[3]

Abd-El-Aziz A.S., 2003, Macromolecules Containing Metal and Metal-Like Elements, Volume 1, A Half-Century of Metal- and Metalloid-Containing Polymers

[4] Benzo[f]- and Benzo[h]Coumarin-Containing poly(methyl methacrylate)s and poly(methyl methacrylate)s with pendant coumarin-containing azo dyes [J].

Abd-El-Aziz, Alaa S. ;

Shipman, Patrick O. ;

Neeland, Edward G. ;

Corkery, T. Christopher ;

Mohammed, Shawkat ;

Harvey, Pierre D. ;

Mohamed, Hany M. ;

Bedair, Ahmed H. ;

El-Agrody, Ahmed M. ;

Aguiar, Pedro M. ;

Kroeker, Scott .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2008, 209 (01) :84-103

[5] Polynorbornenes Containing Ferrocene Derivatives and Alkyne-bis(tricarbonylcobalt) [J].

Abd-El-Aziz, Alaa S. ;

Winram, Diana J. ;

Shipman, Patrick O. ;

Bichler, Lukas .

MACROMOLECULAR RAPID COMMUNICATIONS, 2010, 31 (22) :1992-1997

[6] Synthetic methodologies and properties of organometallic and coordination macromolecules [J].

Abd-El-Aziz, Alaa S. ;

Shipman, Patrick O. ;

Boden, Britta N. ;

McNeil, W. Stephen .

PROGRESS IN POLYMER SCIENCE, 2010, 35 (06) :714-836

[7] Cationic organoiron polyelectrolyte three-arm stars [J].

Abd-El-Aziz, AS ;

Carruthers, SA ;

Todd, EK ;

Afifi, TH ;

Gavina, JMA .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (07) :1382-1396

[8] Soluble polymethacrylates and polystyrenes containing cationic cyclopentadienyliron moieties [J].

Abd-El-Aziz, AS ;

Todd, EK .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2004, 205 (04) :418-429

[9] Organoiron polymers [J].

Abd-El-Aziz, AS ;

Todd, EK .

COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :3-52

[10] Organometallic polymers of the transition metals [J].

Abd-El-Aziz, AS .

MACROMOLECULAR RAPID COMMUNICATIONS, 2002, 23 (17) :995-1031

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