A novel phosphate conversion film on Mg-8.8Li alloy

被引:124
作者
Song, Yingwei [1 ]
Shan, Dayong [1 ]
Chen, Rongshi [1 ]
Zhang, Fan [1 ]
Han, En-Hou [1 ]
机构
[1] Chinese Acad Sci, State Key Lab Corros & Protect, Inst Met Res, Shenyang 110016, Peoples R China
关键词
Phosphate; Conversion film; Mg-Li alloy; Corrosion resistance; AZ91 MAGNESIUM ALLOY; MG-LI ALLOY; CORROSION BEHAVIOR; COATINGS; SURFACE;
D O I
10.1016/j.surfcoat.2008.10.004
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The super light Mg-Li alloys exhibit excellent formability due to the addition of lithium, but the corrosion resistance is deteriorated. A novel conversion film is developed to improve the corrosion resistance. The surface morphology of conversion film was observed using scanning electron microscopy (SEM). The chemical composition was analyzed by X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). The corrosion behaviors of Mg-8.8Li alloy and conversion film were investigated with electrochemical and immersion tests. The experimental results indicated that the Mg-8.8Li alloys with and without the protection of conversion film can both be used in NaOH solution safely. But the Mg-8.8Li substrate was susceptible to corrode in NaCl and Na(2)SO(4) solutions, and the conversion film can prevent them from corroding. Compared with the NaCl solution, the Na(2)SO(4) solution was a strong corrosive medium to the conversion film. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:1107 / 1113
页数:7
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