Hydrothermal Synthesis, Crystal Structure and Characterizations of Two New Manganese(II) Phosphonates with a 3D Framework Structure

被引：6
|
作者：
Zhu, Yan-Yu [1 ]
Li, Jing [1 ]
Sun, Zhen-Gang [1 ]
Zhang, Jing [1 ]
Zhao, Yan [1 ]
Lu, Xin [1 ]
Liu, Lei [1 ]
Zhang, Na [1 ]
机构：
[1] Liaoning Normal Univ, Fac Chem & Chem Engn, Inst Chem Functionalized Mat, Dalian, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2009年 / 635卷 / 01期
关键词：
Manganese; Metal phosphonates; Crystal structures; METAL PHOSPHONATE; MAGNETIC-PROPERTIES;
D O I：
10.1002/zaac.200800377
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new manganese(II) phosphonates, (NH4)Mn-2.5-[(O3PCH(OH)CO2)(2)(H2O)] (1) and [NH3(CH2)(4)NH3](0.5)Mn-2.5-(NH4)Mn-2.5-[(O3PCH(OH)CO2)(2)(H2O)] (2) have been synthesized under hydro thermal conditions and structurally characterized by single-crystal X-ray diffraction as well as with infrared spectroscopy. elemental analysis and thermogravimetric analysis. The two isomorphous compounds feature a 3D framework structure. The Mn(1)O-6 and Mn(3)O-5 polyhedra are bridged by the CPO3 tetralieda into a Mu(II) phosphonate layer in ac-plane. Mn(2)O-6 polyhedra are linked to each other by CPO3 tetralieda to form infinite chains, which are connected to layers by carboxylate groups to form a 3D framework structure with channels along the a- and c-axis. respectively. The NH4+ ions or protonated 1,4-butylenediamine cations are located inside the channels along the a axis.
引用
收藏
页码：171 / 174
页数：4
相关论文
共 50 条
  • [1] Hydrothermal Synthesis, Crystal Structure, and Characterizations of a New Lanthanide Oxalatophosphonate with a 3D Framework Structure
    Zhang, Na
    Huang, Cui-Ying
    Sun, Zhen-Gang
    Liu, Lei
    Hua, Rui-Nian
    Lu, Xin
    Tong, Fei
    Wang, Wei-Nan
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (3-4): : 449 - 453
  • [2] Hydrothermal Synthesis, Crystal Structure and Characterizations of Four New Metal Phosphonates with Layered Structure
    Liu, Lei
    Li, Jing
    Sun, Zhen-Gang
    Dong, Da-Peng
    Zhang, Na
    Lu, Xin
    Wang, Wei-Nan
    Tong, Fei
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (01): : 247 - 252
  • [3] Hydrothermal Synthesis and Crystal Structure of a New 3D Zn(II) Coordination Polymer
    Li, Xianjiang
    Shen, Bo
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (14) : 8235 - 8236
  • [4] Hydrothermal synthesis, crystal structure and characterizations of a lanthanum(III) sulfate oxalate with a 3D network structure
    Yuan, YP
    Song, JL
    Mao, JG
    INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (01) : 24 - 26
  • [5] Hydrothermal Synthesis, Crystal Structures, and Thermal Stabilities of Two New Zinc Phosphonates with a Layered and a 3D Framework Structures
    Lu, Xin
    Li, Jing
    Sun, Zhen-Gang
    Dong, Da-Peng
    Hua, Rui-Nian
    Zhang, Na
    Liu, Lei
    Tong, Fei
    Wang, Wei-Nan
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2009, 635 (15): : 2617 - 2621
  • [6] Hydrothermal syntheses, crystal structures, and thermal stability of two new 3D open-framework metal(II) phosphonates
    Cui, Lianyi
    Sun, Zhengang
    Chen, Hui
    Meng, Lei
    Dong, Dapeng
    Tian, Cuihua
    Zhu, Zaiming
    You, Wansheng
    JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (12) : 1247 - 1254
  • [7] Hydrothermal Synthesis, Crystal Structure, and Characterization of Two New Metal Diphosphonates with a 3D Pillared Layered Structure
    Zhang, Na
    Huang, Cui-Ying
    Sun, Zhen-Gang
    Zhang, Jing
    Liu, Lei
    Lu, Xin
    Wang, Wei-Nan
    Tong, Fei
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (07): : 1405 - 1409
  • [8] Synthesis, structure and characterization of two Pb(II) phosphonates with layered or 3D structures
    Ying, Shao-Ming
    Li, Xin-Fa
    Huang, Jian-Gen
    Lin, Jun-Yue
    Chen, Wen-Tong
    Zhou, Guang-Pei
    INORGANICA CHIMICA ACTA, 2008, 361 (05) : 1547 - 1551
  • [9] Hydrothermal Synthesis, Crystal Structure, and Thermal Stability of Two New Metal Phosphonates with a Pillared Layered Structure
    Zhang, Jing
    Li, Jing
    Sun, Zhen-Gang
    Zhao, Yan
    Zhu, Yan-Yu
    Zhang, Na
    Liu, Lei
    Lu, Xin
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (14): : 2629 - 2633
  • [10] Hydrothermal Synthesis and Crystal Structure of a New Ni(II) Coordination Polymer With Polycatenated 2D+2D→3D Framework
    Li, Hongliang
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2015, 45 (08) : 1132 - 1134
12345