New heteroaromatic polymers consisting of alkyl- and amino-1,3,5-triazine units.: Their basic optical properties and n-type time-of-flight drift mobility

被引：26
作者：
Yamamoto, T
Watanabe, S
Fukumoto, H
Sato, M
Tanaka, T
机构：
[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
[2] Tosoh Corp, Tokyo Res Lab, Ayase, Kanagawa 2521123, Japan
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2006年 / 27卷 / 05期
关键词：
conjugated polymers; carrier mobility; polyaromatics; polycondensation; poly-1,3,5-triazine;
D O I：
10.1002/marc.200500773
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Alternating copolymers between substituted 1,3,5-triazine (substituent = alkyl or amine) and thiophene or bithiophene are synthesized. The copolymer of amino-1,3,5-triazine with thiophene is soluble in organic solvents, transparent in most parts of the visible region, and photoluminescent. The copolymer receives electrochemical n-doping with an E-pc of -2.08 V vs Ag+/Ag and shows a time-of-flight electron drift mobility of 2.0 x 10(-4) cm(2) center dot V-1 center dot s(-1) which is larger than that of widely used Al(8-quinolinolato)(3).
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页码：317 / 321
页数：5
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