Superhydrophobic perfluorinated metal-organic frameworks

被引：187
|
作者：
Chen, Teng-Hao [1 ]
Popov, Ilya [1 ]
Zenasni, Oussama [1 ]
Daugulis, Olafs [1 ]
Miljanic, Ognjen S. [1 ]
机构：
[1] Univ Houston, Dept Chem, Houston, TX 77204 USA
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 61期
基金：
美国国家科学基金会;
关键词：
COPPER-CATALYZED ARYLATION; COORDINATION POLYMERS; CRYSTAL-STRUCTURE; HYDROGEN STORAGE; GENERAL-METHOD; ADSORPTION; DESIGN;
D O I：
10.1039/c3cc41564c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three perfluorinated Cu-based metal-organic frameworks (MOFs) were prepared starting from extensively fluorinated biphenyl-based ligands accessed via C-H functionalization. These new materials are highly hydrophobic: with water contact angles of up to 151 +/- 1 degrees, they are among the most water-repellent MOFs ever reported.
引用
收藏
页码：6846 / 6848
页数：3
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