Probing secondary coordination sphere influence on the oxygenation of zinc alkyls: formation of a unique zinc peroxide species

被引：18

作者：

Sobota, Piotr ^{[1
]}

Petrus, Rafal ^{[1
]}

Zelga, Karolina ^{[2
]}

Makolski, Lukasz ^{[2
]}

Kubicki, Dominik ^{[2
]}

Lewinski, Janusz ^{[2
,3
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

[2] Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland

[3] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 89期

关键词：

COMPLEXES; DIOXYGEN; ACTIVATION; REACTIVITY; LIGAND; ALKYLPEROXIDE; ALKOXIDES; HYDRATION; CLUSTERS; CADMIUM;

D O I：

10.1039/c3cc46206d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of ethylzinc derivatives of o-hydroxybiphenyl with O-2 were investigated. The study revealed an essential role in the oxygenation process of intra-molecular interactions involving aromatic rings and provided a unique aryloxide (hydroxide) Zn-8(OAr)(8)(OH)(6)(O-2) cluster with an encapsulated peroxide species.

引用

收藏

页码：10477 / 10479

页数：3

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