Heterolytic activation of hydrogen gas: New evidence for Spencer-Yu hypothesis!

被引：3

作者：

Faucher, Nicolas ^{[1
]}

Cintrat, Jean-Christophe ^{[1
]}

Rousseau, Bernard ^{[1
]}

机构：

[1] CEA, iBiTec S, Serv Chim Bioorgan & Marguage, F-91191 Gif Sur Yvette, France

来源：

APPLIED CATALYSIS A-GENERAL | 2008年 / 346卷 / 1-2期

关键词：

deuterium; hydrogenolysis; heterogeneous catalysis; organolithium; palladium;

D O I：

10.1016/j.apcata.2008.05.011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrogenolysis or deuterogenolysis of organolithium compounds is described for the first time under heterogeneous catalysis. This work establishes that the carbon-lithium bond can undergo a facile reduction reaction when catalyzed by palladium or platinum catalysts and provides strong evidence for the existence of Pd(delta-)-H(delta+) species. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：86 / 89

页数：4

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