Alcohol and water adsorption in zeolitic imidazolate frameworks

被引:280
作者
Zhang, Ke [1 ]
Lively, Ryan P. [2 ]
Dose, Michelle E. [1 ,2 ]
Brown, Andrew J. [1 ]
Zhang, Chen [1 ]
Chung, Jaeyub [1 ]
Nair, Sankar [1 ]
Koros, William J. [1 ]
Chance, Ronald R. [1 ,2 ]
机构
[1] Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA
[2] Algenol Biofuels, Bonita Springs, FL 34315 USA
关键词
ETHANOL; ENERGY;
D O I
10.1039/c3cc39116g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Alcohol (methanol, ethanol, 1-propanol, 2-propanol and 1-butanol) and water vapor adsorption in zeolitic imidazolate frameworks (ZIF-8, ZIF-71 and ZIF-90) with similar crystal sizes was systematically studied. The feasibility of applying these ZIF materials to the recovery of bio-alcohols is evaluated by estimating the vapor-phase alcohol-water sorption selectivity.
引用
收藏
页码:3245 / 3247
页数:3
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